Diversification of the Renewable Furanic Platform via 5-(Chloromethyl)furfural-Based Carbon Nucleophiles.
5-(chloromethyl)furfural
Darzens reaction
Reformatsky reaction
biobased products
platform molecules
Journal
ChemSusChem
ISSN: 1864-564X
Titre abrégé: ChemSusChem
Pays: Germany
ID NLM: 101319536
Informations de publication
Date de publication:
07 Jan 2021
07 Jan 2021
Historique:
received:
15
07
2020
revised:
16
09
2020
pubmed:
18
9
2020
medline:
18
9
2020
entrez:
17
9
2020
Statut:
ppublish
Résumé
Biobased 5-(chloromethyl)furoate and 5-methylfuroate esters can be deprotonated to function as furylogous lithium enolates, and the former can also undergo zinc insertion to access Reformatsky-type chemistry. Carbon nucleophilicity represents hitherto little-explored reactivity in these key carbohydrate-derived platform molecules, expanding their synthetic utility and potentially opening up new sustainable product markets (e. g., in epoxy resins or biobased dyes).
Identifiants
pubmed: 32941679
doi: 10.1002/cssc.202001718
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
303-305Informations de copyright
© 2020 Wiley-VCH GmbH.
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