Selective Synthesis of Single-Handed Helical Polymers from Achiral Monomer and a Mechanism Study on Helix-Sense-Selective Polymerization.

chiral polymers helix helix-sense-selective polymerization living polymerization polymers

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
11 01 2021
Historique:
received: 26 08 2020
revised: 30 09 2020
pubmed: 3 10 2020
medline: 3 10 2020
entrez: 2 10 2020
Statut: ppublish

Résumé

Inspired by the exquisite helices in Nature, fabrication of helical materials with controlled handedness has attracted considerable attention. Herein, we report on precis synthesis of single left- and right-handed helical polyisocyanides through living polymerization of achiral monomers using chiral palladium catalysts under helix-sense-selective manner. Mechanism study revealed that the yielded helices with opposite handedness showed different activity of the living chain end. The helix with unfavored handedness was self-terminated, while the one with favored handedness showed high activity and could undergo chain propagation to form a high molecular weight polymer with maintained single-handed helicity.

Identifiants

pubmed: 33006185
doi: 10.1002/anie.202011661
doi:

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

806-812

Informations de copyright

© 2020 Wiley-VCH GmbH.

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Auteurs

Li Zhou (L)

Department of polymer science and engineering, School of chemistry and chemical engineering, Anhui Key Lab of Catalytic Materials and Reaction Engineering, Hefei university of Technology, 193 Tunxi Road, Hefei, 230009, Anhui, China.

Xun-Hui Xu (XH)

Department of polymer science and engineering, School of chemistry and chemical engineering, Anhui Key Lab of Catalytic Materials and Reaction Engineering, Hefei university of Technology, 193 Tunxi Road, Hefei, 230009, Anhui, China.

Zhi-Qiang Jiang (ZQ)

Department of polymer science and engineering, School of chemistry and chemical engineering, Anhui Key Lab of Catalytic Materials and Reaction Engineering, Hefei university of Technology, 193 Tunxi Road, Hefei, 230009, Anhui, China.

Lei Xu (L)

Department of polymer science and engineering, School of chemistry and chemical engineering, Anhui Key Lab of Catalytic Materials and Reaction Engineering, Hefei university of Technology, 193 Tunxi Road, Hefei, 230009, Anhui, China.

Ben-Fa Chu (BF)

Department of polymer science and engineering, School of chemistry and chemical engineering, Anhui Key Lab of Catalytic Materials and Reaction Engineering, Hefei university of Technology, 193 Tunxi Road, Hefei, 230009, Anhui, China.

Na Liu (N)

Department of polymer science and engineering, School of chemistry and chemical engineering, Anhui Key Lab of Catalytic Materials and Reaction Engineering, Hefei university of Technology, 193 Tunxi Road, Hefei, 230009, Anhui, China.

Zong-Quan Wu (ZQ)

Department of polymer science and engineering, School of chemistry and chemical engineering, Anhui Key Lab of Catalytic Materials and Reaction Engineering, Hefei university of Technology, 193 Tunxi Road, Hefei, 230009, Anhui, China.

Classifications MeSH