Trimeric uranyl(vi)-citrate forms Na


Journal

Chemical communications (Cambridge, England)
ISSN: 1364-548X
Titre abrégé: Chem Commun (Camb)
Pays: England
ID NLM: 9610838

Informations de publication

Date de publication:
07 Nov 2020
Historique:
pubmed: 3 10 2020
medline: 3 10 2020
entrez: 2 10 2020
Statut: ppublish

Résumé

M. Basile, et al., Chem. Commun., 2015, 51, 5306-5309, showed that a sodium ion is sandwiched by uranyl(vi) oxygen atoms of two 3 : 3 uranyl(vi)-citrate complex molecules in single-crystals. By means of NMR spectroscopy supported by DFT calculations we provide unambiguous evidence for this complex to persist in aqueous solution above a critical concentration of 3 mM uranyl citrate. Unprecedented Ca

Identifiants

pubmed: 33006343
doi: 10.1039/d0cc05460g
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

13133-13136

Auteurs

Jerome Kretzschmar (J)

Helmholtz-Zentrum Dresden-Rossendorf, Institute of Resource Ecology, Bautzner Landstr. 400, 01328 Dresden, Germany. j.kretzschmar@hzdr.de.

Classifications MeSH