Reversible Reductive Elimination in Aluminum(II) Dihydrides.
aluminum
low oxidation state
oxidative addition
reduction
reductive elimination
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
25 Jan 2021
25 Jan 2021
Historique:
received:
20
08
2020
revised:
05
10
2020
pubmed:
7
10
2020
medline:
7
10
2020
entrez:
6
10
2020
Statut:
ppublish
Résumé
Oxidative addition and reductive elimination are defining reactions of transition-metal organometallic chemistry. In main-group chemistry, oxidative addition is now well-established but reductive elimination reactions are not yet general in the same way. Herein, we report dihydrodialanes supported by amidophosphine ligands. The ligand serves as a stereochemical reporter for reversible reductive elimination/oxidative addition chemistry involving Al
Identifiants
pubmed: 33022874
doi: 10.1002/anie.202011418
pmc: PMC7894477
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
2047-2052Subventions
Organisme : H2020 European Research Council
ID : ERC-2016-STG-716315
Organisme : Leverhulme Trust
ID : Philip Leverhulme Prize
Informations de copyright
© 2020 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
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