Structural Snapshots of π-Arene Bonding in a Gold Germylene Cation.
germylenium
gold
group 14 elements
structural snapshot
π-bonding
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
01 Dec 2020
01 Dec 2020
Historique:
received:
14
10
2020
pubmed:
16
10
2020
medline:
16
10
2020
entrez:
15
10
2020
Statut:
ppublish
Résumé
Heavier group 14 element cations exhibit a remarkable reactivity that has typically hampered their isolation. For the few available examples, the role of π-arene interactions is crucial to provide kinetic stabilization, but dynamic and structural information on those contacts is yet limited. In this study we have accessed the metalogermylenium cation [(PMe
Identifiants
pubmed: 33058332
doi: 10.1002/chem.202004566
pmc: PMC7756455
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
15519-15523Subventions
Organisme : H2020 European Research Council
ID : ERC Starting Grant, CoopCat, Project 756575
Informations de copyright
© 2020 Wiley-VCH GmbH.
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