Isomerization Reactions in Anionic Mesoionic Carbene-Borates and Control of Properties and Reactivities in the Resulting Co

cobalt ligand rearrangement mesoionic carbene reactivity spin state

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
04 Jan 2021
Historique:
received: 04 10 2020
pubmed: 21 10 2020
medline: 21 10 2020
entrez: 20 10 2020
Statut: ppublish

Résumé

We present herein anionic borate-based bi-mesoionic carbene compounds of the 1,2,3-triazol-4-ylidene type that undergo C-N isomerization reactions. The isomerized compounds are excellent ligands for Co

Identifiants

pubmed: 33080102
doi: 10.1002/anie.202013376
pmc: PMC7839553
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

499-506

Subventions

Organisme : Deutsche Forschungsgemeinschaft
ID : SA 1840/7-1
Organisme : Alexander von Humboldt-Stiftung
ID : Research Award
Organisme : Alexander von Humboldt-Stiftung
ID : Post-doctoral fellowship

Informations de copyright

© 2020 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.

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Auteurs

Jessica Stubbe (J)

Institut für Chemie und Biochemie, Anorganische Chemie, Freie Universität Berlin, Fabeckstrasse 34-36, 14195, Berlin, Germany.

Nicolás I Neuman (NI)

Institut für Chemie und Biochemie, Anorganische Chemie, Freie Universität Berlin, Fabeckstrasse 34-36, 14195, Berlin, Germany.
Instituto de Desarrollo Tecnológico para la Industria Química CCT Santa Fe CONICET-UNL, Colectora Ruta Nacional 168, Km 472, Paraje El Pozo, 3000, Santa Fe, Argentina.

Ross McLellan (R)

WestCHEM, Department of Pure & Applied Chemistry, University of Strathclyde, Glasgow, G1 1XL, UK.

Michael G Sommer (MG)

Institut für Chemie und Biochemie, Anorganische Chemie, Freie Universität Berlin, Fabeckstrasse 34-36, 14195, Berlin, Germany.

Maite Nößler (M)

Institut für Chemie und Biochemie, Anorganische Chemie, Freie Universität Berlin, Fabeckstrasse 34-36, 14195, Berlin, Germany.

Julia Beerhues (J)

Lehrstuhl für Anorganische Koordinationschemie, Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, 70569, Stuttgart, Germany.

Robert E Mulvey (RE)

WestCHEM, Department of Pure & Applied Chemistry, University of Strathclyde, Glasgow, G1 1XL, UK.

Biprajit Sarkar (B)

Institut für Chemie und Biochemie, Anorganische Chemie, Freie Universität Berlin, Fabeckstrasse 34-36, 14195, Berlin, Germany.
Lehrstuhl für Anorganische Koordinationschemie, Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, 70569, Stuttgart, Germany.

Classifications MeSH