Multi-Mode Color-Tunable Long Persistent Luminescence in Single-Component Coordination Polymers.

cadmium color tuning coordination polymers halides long persistent luminescence (LPL)

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
01 Feb 2021
Historique:
received: 22 09 2020
pubmed: 23 10 2020
medline: 23 10 2020
entrez: 22 10 2020
Statut: ppublish

Résumé

Materials with tunable long persistent luminescence (LPL) properties have wide applications in security signs, anti-counterfeiting, data encrypting, and other fields. However, the majority of reported tunable LPL materials are pure organic molecules or polymers. Herein, a series of metal-organic coordination polymers displaying color-tunable LPL were synthesized by the self-assembly of HTzPTpy ligand with different cadmium halides (X=Cl, Br, and I). In the solid state, their LPL emission colors can be tuned by the time-evolution, as well as excitation and temperature variation, realizing multi-mode dynamic color tuning from green to yellow or green to red, and are the first such examples in single-component coordination polymer materials. Single-crystal X-ray diffraction analysis and theoretical calculations reveal that the modification of LPL is due to the balanced action from single molecule and aggregate triplet excited states caused by an external heavy-atom effect. The results show that the rational introduction of different halide anions into coordination polymers can realize multi-color LPL.

Identifiants

DOI: 10.1002/anie.202012831 PMID: 33089599
pubmed: 33089599
doi: 10.1002/anie.202012831
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

2526-2533

Subventions

Organisme : National Natural Science Foundation of China
ID : 21771197, 21821003, 21720102007, 21890380
Organisme : Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program
ID : 2017BT01C161
Organisme : Fundamental Research Funds for Central Universities

Informations de copyright

© 2020 Wiley-VCH GmbH.

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Auteurs

Zheng Wang (Z)

MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275, China.
College of Chemistry and Chemical Engineering, Key Laboratory of Chemical Additives for China National Light Industry, Shaanxi University of Science and Technology, Xi'an, 710021, China.

Cheng-Yi Zhu (CY)

MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275, China.

Jun-Ting Mo (JT)

MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275, China.

Xian-Yan Xu (XY)

College of Chemistry and Civil Engineering, Shaoguan University, Shaoguan, 512005, China.

Jia Ruan (J)

MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275, China.

Mei Pan (M)

MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275, China.
ORCID: 0000-0002-8979-7305

Cheng-Yong Su (CY)

MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275, China.

Classifications MeSH