Synthesis and Coordination Ability of a Donor-Stabilised Bis-Phosphinidene.
bimetallic
catalysis
chelating ligands
main group elements
phosphinidene
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
01 Feb 2021
01 Feb 2021
Historique:
received:
22
09
2020
revised:
23
10
2020
pubmed:
27
10
2020
medline:
27
10
2020
entrez:
26
10
2020
Statut:
ppublish
Résumé
Chelating phosphines have long been a mainstay as efficient directing ligands in transition-metal catalysis. Low-valent derivatives, namely chelating phosphinidenes, are to date unknown, and could lead to chelating complexes containing more than one metal centre due to the intrisic capacity of phosphinidenes to bind two metal fragments at one P-centre. Here we describe the synthesis of the first such chelating bis-phosphinidene ligand, XantP
Identifiants
pubmed: 33105041
doi: 10.1002/chem.202004300
pmc: PMC7898926
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
2476-2482Subventions
Organisme : DFG
ID : EXC 2008 - 390540038
Organisme : DFG
ID : DR-226-17/3
Informations de copyright
© 2020 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH.
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