Design, synthesis, molecular docking and anti-proliferative evaluations of [1,2,4]triazolo[4,3-a]quinoxaline derivatives as DNA intercalators and Topoisomerase II inhibitors.


Journal

Bioorganic chemistry
ISSN: 1090-2120
Titre abrégé: Bioorg Chem
Pays: United States
ID NLM: 1303703

Informations de publication

Date de publication:
12 2020
Historique:
received: 26 06 2020
revised: 27 09 2020
accepted: 17 10 2020
pubmed: 29 10 2020
medline: 17 6 2021
entrez: 28 10 2020
Statut: ppublish

Résumé

In view of their DNA intercalation activities as anticancer agents, novel twenty four [1,2,4]triazolo[4,3-a]quinoxaline derivatives have been designed, synthesized and evaluated against HepG2, HCT-116 and MCF-7 as DNA intercalators and Top II enzyme inhibitors. The data obtained from molecular modeling studies revealed that, our small aromatic molecules were concluded to act through two ways firstly, through non-covalent interaction with the directly bound proteins to DNA hence inhibit topoisomerase-II enzyme. The second is through non-covalently binding to double helical structures of DNA either by intercalating binder as in compounds 10

Identifiants

pubmed: 33113414
pii: S0045-2068(20)31697-7
doi: 10.1016/j.bioorg.2020.104399
pii:
doi:

Substances chimiques

1,2,4-triazolo(4,3-a)quinoxaline 0
Antineoplastic Agents 0
Intercalating Agents 0
Quinoxalines 0
Topoisomerase II Inhibitors 0
Triazoles 0
DNA 9007-49-2
calf thymus DNA 91080-16-9
DNA Topoisomerases, Type II EC 5.99.1.3

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

104399

Informations de copyright

Copyright © 2020 Elsevier Inc. All rights reserved.

Auteurs

Khaled El-Adl (K)

Pharmaceutical Medicinal Chemistry and Drug Design Department, Faculty of Pharmacy (Boys), Al-Azhar University, Nasr City 11884, Cairo, Egypt; Pharmaceutical Chemistry Department, Faculty of Pharmacy, Heliopolis University for Sustainable Development, Cairo, Egypt. Electronic address: eladlkhaled74@yahoo.com.

Abdel-Ghany A El-Helby (AA)

Pharmaceutical Medicinal Chemistry and Drug Design Department, Faculty of Pharmacy (Boys), Al-Azhar University, Nasr City 11884, Cairo, Egypt.

Helmy Sakr (H)

Pharmaceutical Medicinal Chemistry and Drug Design Department, Faculty of Pharmacy (Boys), Al-Azhar University, Nasr City 11884, Cairo, Egypt.

Alaa Elwan (A)

Pharmaceutical Medicinal Chemistry and Drug Design Department, Faculty of Pharmacy (Boys), Al-Azhar University, Nasr City 11884, Cairo, Egypt. Electronic address: alaaelwan34@gmail.com.

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Classifications MeSH