From platinum atoms in molecules to colloidal nanoparticles: A review on reduction, nucleation and growth mechanisms.

Platinum (Pt) is one of the most studied materials in catalysis today and considered for a wide range of applications: chemical synthesis, energy conversion, air treatment, water purification, sensing, medicine etc. As a limited and non-renewable resource, optimized used of Pt is key. Nanomaterial design offers multiple opportunities to make the most of Pt resources down to the atomic scale. In particular, colloidal syntheses of Pt nanoparticles are well documented and simple to implement, which accounts for the large interest in research and development. For further breakthroughs in the design of Pt nanomaterials, a deeper understanding of the intricate synthesis-structures-properties relations of Pt nanoparticles must be obtained. Understanding how Pt nanoparticles form from molecular precursors is both a challenging and rewarding area of investigation. It is directly relevant to develop improved Pt nanomaterials but is also a source of inspiration to design other precious metal nanostructures. Here, we review the current understanding of Pt nanoparticle formation. This review is aimed at readers with interest in Pt nanoparticles in general and their colloidal syntheses in particular. Readers with a strongest interest on the study of nanomaterial formation will find here the case study of Pt. The preferred model systems and characterization techniques used to perform the study of Pt nanoparticle syntheses are discussed. In light of recent achievements, further direction and areas of research are proposed.

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