Porphyrins Through the Looking Glass: Spectroscopic and Mechanistic Insights in Supramolecular Chirogenesis of New Self-Assembled Porphyrin Derivatives.
chirality
circular dichroism
porphyrins
self-assembly
supramolecular chemistry
supramolecular chirogenesis
Journal
Frontiers in chemistry
ISSN: 2296-2646
Titre abrégé: Front Chem
Pays: Switzerland
ID NLM: 101627988
Informations de publication
Date de publication:
2020
2020
Historique:
received:
27
07
2020
accepted:
09
09
2020
entrez:
16
11
2020
pubmed:
17
11
2020
medline:
17
11
2020
Statut:
epublish
Résumé
The solvent driven aggregation of porphyrin derivatives, covalently linked to a L- or D-prolinate enantiomer, results in the stereospecific formation of species featuring remarkable supramolecular chirality, as a consequence of reading and amplification of the stereochemical information stored in the proline-appended group. Spectroscopic, kinetic, and topographic SEM studies gave important information on the aggregation processes, and on the structures of the final chiral architectures. The results obtained may be the seeds for the construction of stereoselective sensors aiming at the detection, for example, of novel emergent pollutants from agrochemical, food, and pharmaceutical industry.
Identifiants
pubmed: 33195087
doi: 10.3389/fchem.2020.587842
pmc: PMC7593786
doi:
Types de publication
Journal Article
Langues
eng
Pagination
587842Informations de copyright
Copyright © 2020 Stefanelli, Savioli, Zurlo, Magna, Belviso, Marsico, Superchi, Venanzi, Di Natale, Paolesse and Monti.
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