Polymerization-Driven Photoluminescence in Alkanolamine-Based C-Dots.
carbon dots
fluorophores
nanoparticles
photoluminescence
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
01 Feb 2021
01 Feb 2021
Historique:
received:
05
10
2020
revised:
03
11
2020
pubmed:
17
11
2020
medline:
17
11
2020
entrez:
16
11
2020
Statut:
ppublish
Résumé
Carbonized polymer dots (CPDs), a peculiar type of carbon dots, show extremely high quantum yields, making them very attractive nanostructures for application in optics and biophotonics. The origin of the strong photoluminescence of CPDs resides in a complicated interplay of several radiative mechanisms. To understand the correlation between CPD processing and properties, the early stage formation of carbonized polymer dots has been studied. In the synthesis, citric acid monohydrate and 2-amino-2-(hydroxymethyl)propane-1,3-diol have been thermally degraded at 180 °C. The use of an oil bath instead of a more traditional hydrothermal reactor has allowed the CPD properties to be monitored at different reactions times. Transmission electron microscopy, time-resolved photoluminescence, nuclear magnetic resonance, infrared, and Raman spectroscopy have revealed the formation of polymeric species with amide and ester bonds. Quantum chemistry calculations have been employed to investigate the origin of CPD electronic transitions. At short reaction times, amorphous C-dots with 80 % quantum yield, have been obtained.
Identifiants
pubmed: 33196126
doi: 10.1002/chem.202004465
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
2543-2550Subventions
Organisme : Ministero dell'Istruzione, dell'Università e della Ricerca
ID : PRIN 2017W75RAE
Organisme : Ministero dell'Istruzione, dell'Università e della Ricerca
ID : PON linea 1
Informations de copyright
© 2020 Wiley-VCH GmbH.
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