Benzophenothiazine and Its Cr(III)-Catalyzed Cross Dehydrogenative Couplings.


Journal

Organic letters
ISSN: 1523-7052
Titre abrégé: Org Lett
Pays: United States
ID NLM: 100890393

Informations de publication

Date de publication:
04 12 2020
Historique:
pubmed: 17 11 2020
medline: 17 11 2020
entrez: 16 11 2020
Statut: ppublish

Résumé

In stark contrast to phenothiazines and their prevalence for cross-dehydrogenative amination reactions, benzophenothiazine has a pronounced preference for cross-dehydrogenative C-C bond-forming reactions. Moreover, the substrate is very versatile, leading to several new classes of C-C bond-forming reactions and many new oxidative coupling product architectures, including unprecedented indole fused paddlewheel-like structures.

Identifiants

pubmed: 33196197
doi: 10.1021/acs.orglett.0c03354
pmc: PMC8046291
doi:

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

9196-9198

Références

Chemistry. 2018 Aug 14;24(46):11936-11943
pubmed: 29766577
Org Lett. 2016 Jul 15;18(14):3326-9
pubmed: 27364730
Angew Chem Int Ed Engl. 2018 Apr 16;57(17):4737-4741
pubmed: 29498166
J Am Chem Soc. 2016 Feb 24;138(7):2411-25
pubmed: 26820243
Acc Chem Res. 2009 Feb 17;42(2):335-44
pubmed: 19220064
Chem Rev. 2010 Aug 11;110(8):4489-97
pubmed: 20380420
Angew Chem Int Ed Engl. 2015 Mar 23;54(13):4102-4
pubmed: 25655504
Org Lett. 2020 Mar 6;22(5):1765-1770
pubmed: 32049541
Chem Commun (Camb). 2019 Apr 9;55(30):4371-4374
pubmed: 30912541
Angew Chem Int Ed Engl. 2014 Jan 3;53(1):74-100
pubmed: 24214829
Nat Prod Rep. 2013 May;30(5):694-752
pubmed: 23467716
Molecules. 2013 Jun 06;18(6):6620-62
pubmed: 23743888
Acc Chem Res. 2019 Jan 15;52(1):161-169
pubmed: 30376296
Chemistry. 2017 May 2;23(25):5972-5977
pubmed: 28009492
Chem Rev. 2011 Mar 9;111(3):1215-92
pubmed: 21391561
J Am Chem Soc. 2018 Oct 17;140(41):13128-13135
pubmed: 30260638
Org Lett. 2018 May 18;20(10):2884-2887
pubmed: 29701985
Chem Commun (Camb). 2018 Nov 15;54(92):13022-13025
pubmed: 30403232

Auteurs

Christina L Bub (CL)

Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany.

Vinzenz Thönnißen (V)

Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany.

Frederic W Patureau (FW)

Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany.

Classifications MeSH