Encapsulation of Graphene in the Hydrophobic Core of a Lipid Bilayer.


Journal

Langmuir : the ACS journal of surfaces and colloids
ISSN: 1520-5827
Titre abrégé: Langmuir
Pays: United States
ID NLM: 9882736

Informations de publication

Date de publication:
08 12 2020
Historique:
pubmed: 25 11 2020
medline: 25 11 2020
entrez: 24 11 2020
Statut: ppublish

Résumé

Theoretical simulations have predicted that a lipid bilayer forms a stable superstructure when a sheet of graphene is inserted in its hydrophobic core. We experimentally produced for the first time a lipid-graphene-lipid assembly by combining the Langmuir-Blodgett and the Langmuir-Schaefer methods. Graphene is sandwiched and remains flat within the hydrophobic core of the lipid bilayer. Using infrared spectroscopy, ellipsometry, and neutron reflectometry, we characterized the superstructure at every fabrication step. The hybrid superstructure is mechanically stable and graphene does not disturb the natural lipid bilayer structure.

Identifiants

pubmed: 33232163
doi: 10.1021/acs.langmuir.0c01691
pmc: PMC7726894
doi:

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

14478-14482

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Auteurs

Hadi Arjmandi-Tash (H)

Department of Supramolecular & Biomaterials Chemistry, Leiden Institute of Chemistry, Leiden University, P.O. Box 9502, 2300 RA Leiden, The Netherlands.

Lia M C Lima (LMC)

Department of Supramolecular & Biomaterials Chemistry, Leiden Institute of Chemistry, Leiden University, P.O. Box 9502, 2300 RA Leiden, The Netherlands.

Liubov A Belyaeva (L)

Department of Supramolecular & Biomaterials Chemistry, Leiden Institute of Chemistry, Leiden University, P.O. Box 9502, 2300 RA Leiden, The Netherlands.

Tetiana Mukhina (T)

Institut Laue-Langevin, 71 Avenue des Martyrs, BP 156, 38042 Grenoble, France.
Institut Charles Sadron (ICS), UPR22 CNRS, Université de Strasbourg, 23 Rue du Lœss, 67034 Strasbourg, France.

Giovanna Fragneto (G)

Institut Laue-Langevin, 71 Avenue des Martyrs, BP 156, 38042 Grenoble, France.

Alexander Kros (A)

Department of Supramolecular & Biomaterials Chemistry, Leiden Institute of Chemistry, Leiden University, P.O. Box 9502, 2300 RA Leiden, The Netherlands.

Thierry Charitat (T)

Institut Charles Sadron (ICS), UPR22 CNRS, Université de Strasbourg, 23 Rue du Lœss, 67034 Strasbourg, France.

Grégory F Schneider (GF)

Department of Supramolecular & Biomaterials Chemistry, Leiden Institute of Chemistry, Leiden University, P.O. Box 9502, 2300 RA Leiden, The Netherlands.

Classifications MeSH