BN-Doped Metal-Organic Frameworks: Tailoring 2D and 3D Porous Architectures through Molecular Editing of Borazines.
BN-doping
borazine
gas adsorption
heteroatom doping
meta-organic frameworks
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
24 Feb 2021
24 Feb 2021
Historique:
received:
20
10
2020
pubmed:
1
12
2020
medline:
1
12
2020
entrez:
30
11
2020
Statut:
ppublish
Résumé
Building on the MOF approach to prepare porous materials, herein we report the engineering of porous BN-doped materials using tricarboxylic hexaarylborazine ligands, which are laterally decorated with functional groups at the full-carbon 'inner shell'. Whilst an open porous 3D entangled structure could be obtained from the double interpenetration of two identical metal frameworks derived from the methyl substituted borazine, the chlorine-functionalised linker undergoes formation of a porous layered 2D honeycomb structure, as shown by single-crystal X-ray diffraction analysis. In this architecture, the borazine cores are rotated by 60° in alternating layers, thus generating large rhombohedral channels running perpendicular to the planes of the networks. An analogous unsubstituted full-carbon metal framework was synthesised for comparison. The resulting MOF revealed a crystalline 3D entangled porous structure, composed by three mutually interpenetrating networks, hence denser than those obtained from the borazine linkers. Their microporosity and CO
Identifiants
pubmed: 33252163
doi: 10.1002/chem.202004640
pmc: PMC7986190
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
4124-4133Subventions
Organisme : H2020-MSCA-RISE-2016
ID : 734834
Organisme : OMCAMOF
ID : 2453712F
Informations de copyright
© 2020 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH.
Références
Nature. 2004 Feb 5;427(6974):523-7
pubmed: 14765190
Chem Soc Rev. 2017 Jun 6;46(11):3242-3285
pubmed: 28462954
Chem Soc Rev. 2017 Jun 6;46(11):3402-3430
pubmed: 28555216
Chem Soc Rev. 2017 Jun 6;46(11):3302-3321
pubmed: 28422212
Science. 2001 Feb 9;291(5506):1021-3
pubmed: 11161211
Chem Soc Rev. 2018 Jan 22;47(2):533-557
pubmed: 29112210
Chemistry. 2014 Sep 8;20(37):11856-62
pubmed: 25079120
Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55
pubmed: 19171970
Langmuir. 2015 May 5;31(17):4988-95
pubmed: 25865754
Chem Soc Rev. 2017 Jun 6;46(11):3104-3107
pubmed: 28561090
Chem Soc Rev. 2015 Sep 21;44(18):6616-43
pubmed: 26186682
Chemistry. 2015 Feb 23;21(9):3528-39
pubmed: 25469827
Environ Sci Technol. 2010 Mar 1;44(5):1820-6
pubmed: 20143826
Nat Mater. 2019 Jul;18(7):740-745
pubmed: 31086318
Angew Chem Int Ed Engl. 2017 Apr 10;56(16):4483-4487
pubmed: 28323375
Chem Soc Rev. 2017 Jun 6;46(11):3322-3356
pubmed: 28224148
J Am Chem Soc. 2006 Feb 1;128(4):1304-15
pubmed: 16433549
ACS Nano. 2017 Oct 24;11(10):10003-10011
pubmed: 28892607
Angew Chem Int Ed Engl. 2008;47(2):242-4
pubmed: 18000932
Angew Chem Int Ed Engl. 2013 Jul 15;52(29):7410-4
pubmed: 23737102
Chemistry. 2016 Sep 5;22(37):12972-82
pubmed: 27439948
Chem Rev. 2020 Feb 26;120(4):2171-2214
pubmed: 31990527
Science. 2010 Jul 23;329(5990):424-8
pubmed: 20595583
Chemistry. 2020 May 20;26(29):6608-6621
pubmed: 32023358
Chemistry. 2021 Feb 24;27(12):4124-4133
pubmed: 33252163
J Am Chem Soc. 2017 Apr 19;139(15):5503-5519
pubmed: 28276248
Acta Crystallogr C Struct Chem. 2018 Feb 1;74(Pt 2):113-119
pubmed: 29400323
Chem Soc Rev. 2014 Aug 21;43(16):6062-96
pubmed: 24875583
Chem Commun (Camb). 2016 Feb 28;52(17):3552-5
pubmed: 26843436
Dalton Trans. 2012 Mar 21;41(11):3119-22
pubmed: 22318553
Chem Commun (Camb). 2015 Oct 25;51(83):15222-36
pubmed: 26411675
Chemistry. 2013 Jun 10;19(24):7771-9
pubmed: 23616404
Nanotechnology. 2013 Apr 19;24(15):155603
pubmed: 23518673
Chem Rev. 2017 Feb 22;117(4):3479-3716
pubmed: 27258218
Chem Soc Rev. 2020 Feb 10;49(3):708-735
pubmed: 31993598
Chem Commun (Camb). 2014 Jun 21;50(49):6498-501
pubmed: 24816493
ACS Omega. 2019 May 28;4(5):9343-9351
pubmed: 31460023
Science. 2015 May 29;348(6238):aaa8075
pubmed: 26023142
J Am Chem Soc. 2015 Feb 25;137(7):2651-7
pubmed: 25642977
Chem Rev. 2017 Feb 8;117(3):1515-1563
pubmed: 28035812
Proc Natl Acad Sci U S A. 2017 Jul 25;114(30):7923-7928
pubmed: 28696307
J Am Chem Soc. 2016 Jul 20;138(28):8912-9
pubmed: 27345035
Sci Rep. 2013 Nov 13;3:3208
pubmed: 24220570
Chemistry. 2018 Jul 5;24(38):9565-9571
pubmed: 29701892
Langmuir. 2010 Apr 20;26(8):5808-14
pubmed: 20143886
J Am Chem Soc. 2013 Nov 27;135(47):17731-4
pubmed: 24180695
J Org Chem. 2019 Jul 19;84(14):9101-9116
pubmed: 31282157
Chimia (Aarau). 2017 Sep 27;71(9):550-557
pubmed: 30188283
Angew Chem Int Ed Engl. 2009;48(14):2542-5
pubmed: 19241428