Atomic Dislocations and Bond Rupture Govern Dissolution Enhancement under Acoustic Stimulation.

acoustic stimulation activation energy atomic bond rupture mineral dissolution molecular dynamics simulations

Journal

ACS applied materials & interfaces
ISSN: 1944-8252
Titre abrégé: ACS Appl Mater Interfaces
Pays: United States
ID NLM: 101504991

Informations de publication

Date de publication:
09 Dec 2020
Historique:
pubmed: 2 12 2020
medline: 2 12 2020
entrez: 1 12 2020
Statut: ppublish

Résumé

By focusing the power of sound, acoustic stimulation (i.e., often referred to as sonication) enables numerous "green chemistry" pathways to enhance chemical reaction rates, for instance, of mineral dissolution in aqueous environments. However, a clear understanding of the atomistic mechanism(s) by which acoustic stimulation promotes mineral dissolution remains unclear. Herein, by combining nanoscale observations of dissolving surface topographies using vertical scanning interferometry, quantifications of mineral dissolution rates via analysis of solution compositions using inductively coupled plasma optical emission spectrometry, and classical molecular dynamics simulations, we reveal how acoustic stimulation induces dissolution enhancement. Across a wide range of minerals (Mohs hardness ranging from 3 to 7, surface energy ranging from 0.3 to 7.3 J/m

Identifiants

DOI: 10.1021/acsami.0c16424 PMID: 33258375
pubmed: 33258375
doi: 10.1021/acsami.0c16424
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

55399-55410

Auteurs

Longwen Tang (L)

Physics of AmoRphous and Inorganic Solids Laboratory (PARISlab), Department of Civil and Environmental Engineering, University of California, Los Angeles, California 90095, United States.

Shiqi Dong (S)

Laboratory for the Chemistry of Construction Materials (LC2), Department of Civil and Environmental Engineering, University of California, Los Angeles, California 90095, United States.
Department of Materials Science and Engineering, University of California, Los Angeles, California 90095, United States.
Institute for Carbon Management (ICM), University of California, Los Angeles, California 90095, United States.

Ross Arnold (R)

Laboratory for the Chemistry of Construction Materials (LC2), Department of Civil and Environmental Engineering, University of California, Los Angeles, California 90095, United States.
Institute for Carbon Management (ICM), University of California, Los Angeles, California 90095, United States.

Erika Callagon La Plante (EC)

Department of Materials Science and Engineering, University of Texas at Arlington, Arlington, Texas 76019, United States.
ORCID: 0000-0002-5273-9523

Juan Carlos Vega-Vila (JC)

Institute for Carbon Management (ICM), University of California, Los Angeles, California 90095, United States.
Department of Chemical and Biomolecular Engineering, University of California, Los Angeles, California 90095, United States.

Dale Prentice (D)

Laboratory for the Chemistry of Construction Materials (LC2), Department of Civil and Environmental Engineering, University of California, Los Angeles, California 90095, United States.
Institute for Carbon Management (ICM), University of California, Los Angeles, California 90095, United States.

Kirk Ellison (K)

Electric Power Research Institute (EPRI), Charlotte, North Carolina 28262-8550, United States.

Aditya Kumar (A)

Department of Materials Science and Engineering, Missouri University of Science and Technology, Rolla, Missouri 65409, United States.
ORCID: 0000-0001-7550-8034

Narayanan Neithalath (N)

School of Sustainable Engineering and the Built Environment, Arizona State University, Tempe, Arizona 85281, United States.

Dante Simonetti (D)

Institute for Carbon Management (ICM), University of California, Los Angeles, California 90095, United States.
Department of Chemical and Biomolecular Engineering, University of California, Los Angeles, California 90095, United States.
ORCID: 0000-0002-5708-460X

Gaurav Sant (G)

Laboratory for the Chemistry of Construction Materials (LC2), Department of Civil and Environmental Engineering, University of California, Los Angeles, California 90095, United States.
Department of Materials Science and Engineering, University of California, Los Angeles, California 90095, United States.
Institute for Carbon Management (ICM), University of California, Los Angeles, California 90095, United States.
California Nanosystems Institute (CNSI), University of California, Los Angeles, California 90095, United States.
ORCID: 0000-0002-1124-5498

Mathieu Bauchy (M)

Physics of AmoRphous and Inorganic Solids Laboratory (PARISlab), Department of Civil and Environmental Engineering, University of California, Los Angeles, California 90095, United States.
Institute for Carbon Management (ICM), University of California, Los Angeles, California 90095, United States.
ORCID: 0000-0003-4600-0631

Classifications MeSH