A comprehensive study of the sorption mechanism and thermodynamics of f-element sorption onto K-feldspar.

Actinides K-feldspar Sorption Surface complexation model TRLFS Trivalent metal ions

Journal

Journal of colloid and interface science
ISSN: 1095-7103
Titre abrégé: J Colloid Interface Sci
Pays: United States
ID NLM: 0043125

Informations de publication

Date de publication:
Jun 2021
Historique:
received: 22 07 2020
revised: 22 10 2020
accepted: 09 11 2020
pubmed: 7 12 2020
medline: 7 12 2020
entrez: 6 12 2020
Statut: ppublish

Résumé

The mobility of heavy metal contaminants and radionuclides in the environment is directly controlled by their interactions with charged mineral surfaces, hence an assessment of their potential toxicity, e.g. in the context of radioactive waste disposal sites, requires understanding of sorption processes on the molecular level. Here, we investigate the sorption of a variety of rare earth elements (REE) and trivalent actinides (Am, Cm) on K-feldspar using batch sorption, time-resolved laser-induced fluorescence spectroscopy (TRLFS), and a surface complexation model. Initially, a reliable pK

Identifiants

pubmed: 33279214
pii: S0021-9797(20)31544-7
doi: 10.1016/j.jcis.2020.11.041
pii:
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

490-499

Informations de copyright

Copyright © 2020 Elsevier Inc. All rights reserved.

Déclaration de conflit d'intérêts

Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Auteurs

J Neumann (J)

Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Bautzner Landstraße 400, 01328 Dresden, Germany. Electronic address: j.neumann@hzdr.de.

H Brinkmann (H)

Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Bautzner Landstraße 400, 01328 Dresden, Germany. Electronic address: h.brinkmann@hzdr.de.

S Britz (S)

Gesellschaft für Anlagen- und Reaktorsicherheit (GRS) gGmbH, Theodor-Heuss-Straße 4, 38122 Braunschweig, Germany. Electronic address: Susan.Britz@grs.de.

J Lützenkirchen (J)

Karlsruher Institut für Technologie (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany. Electronic address: johannes.luetzenkirchen@kit.edu.

F Bok (F)

Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Bautzner Landstraße 400, 01328 Dresden, Germany. Electronic address: f.bok@hzdr.de.

M Stockmann (M)

Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Bautzner Landstraße 400, 01328 Dresden, Germany. Electronic address: m.stockmann@hzdr.de.

V Brendler (V)

Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Bautzner Landstraße 400, 01328 Dresden, Germany. Electronic address: v.brendler@hzdr.de.

T Stumpf (T)

Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Bautzner Landstraße 400, 01328 Dresden, Germany. Electronic address: t.stumpf@hzdr.de.

M Schmidt (M)

Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Bautzner Landstraße 400, 01328 Dresden, Germany. Electronic address: moritz.schmidt@hzdr.de.

Classifications MeSH