Spent Li-Ion Battery Graphite Turned Into Valuable and Active Catalyst for Electrochemical Oxygen Reduction.

circular economy graphene oxide nitrogen-doped graphene oxygen reduction reaction recycling of Li-ion battery

Journal

ChemSusChem
ISSN: 1864-564X
Titre abrégé: ChemSusChem
Pays: Germany
ID NLM: 101319536

Informations de publication

Date de publication:
18 Feb 2021
Historique:
received: 27 11 2020
pubmed: 15 12 2020
medline: 15 12 2020
entrez: 14 12 2020
Statut: ppublish

Résumé

Employing Li-ion batteries (LIBs) in portable electronics has become a necessity in the modern world but, due to the short application time for any given battery (1-3 years), the quantity of spent LIBs (SLIBs) waste is becoming substantial. Herein, a novel strategy for recycling SLIB graphite and reforming it as a valuable catalyst material for electrochemical oxygen reduction reaction was proposed. SLIB graphite has been used as a precursor material for graphite oxide, which was thereafter doped with nitrogen to prepare nitrogen-doped graphene (NG-Bat). The prepared NG-Bat was characterized by various physical characterization methods and the electrochemical properties of the resulting catalyst material were investigated in alkaline media. It was found that NG-Bat prepared from SLIB had superior physical and electrochemical properties in comparison to commercial nitrogen-doped graphene. The findings clearly demonstrate the importance of the recycling of SLIB graphite and its great potential to be re-applied for various applications.

Identifiants

pubmed: 33314598
doi: 10.1002/cssc.202002742
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

1103-1111

Subventions

Organisme : Estonian Research Council
ID : PSG312
Organisme : Estonian Research Council
ID : IUT19-28
Organisme : Estonian Research Council
ID : TK-141
Organisme : ERA.Net RUS
ID : HeDoCat
Organisme : European Regional Development Fund
ID : 2014-2020.4.01.16-0041
Organisme : European Regional Development Fund
ID : 2014-2020.4.01.15-0005
Organisme : University of California at Berkeley

Informations de copyright

© 2020 Wiley-VCH GmbH.

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Auteurs

Kerli Liivand (K)

National Institute of Chemical Physics and Biophysics, Akadeemia tee 23, 12618, Tallinn, Estonia.

Maryam Kazemi (M)

National Institute of Chemical Physics and Biophysics, Akadeemia tee 23, 12618, Tallinn, Estonia.

Peter Walke (P)

Department of Materials and Environmental Technology, Tallinn University of Technology, Ehitajate Tee 5, 19086, Tallinn, Estonia.

Valdek Mikli (V)

Department of Materials and Environmental Technology, Tallinn University of Technology, Ehitajate Tee 5, 19086, Tallinn, Estonia.

Mai Uibu (M)

Department of Materials and Environmental Technology, Tallinn University of Technology, Ehitajate Tee 5, 19086, Tallinn, Estonia.

Digby D Macdonald (DD)

Department of Nuclear Engineering, University of California at Berkeley, Etcheverry Hall, 2521 Hearst Ave, Berkeley, CA 94709, USA.

Ivar Kruusenberg (I)

National Institute of Chemical Physics and Biophysics, Akadeemia tee 23, 12618, Tallinn, Estonia.
Department of Nuclear Engineering, University of California at Berkeley, Etcheverry Hall, 2521 Hearst Ave, Berkeley, CA 94709, USA.

Classifications MeSH