Complementary Base Lowers the Barrier in SuFEx Click Chemistry for Primary Amine Nucleophiles.
Journal
ACS omega
ISSN: 2470-1343
Titre abrégé: ACS Omega
Pays: United States
ID NLM: 101691658
Informations de publication
Date de publication:
08 Dec 2020
08 Dec 2020
Historique:
received:
16
10
2020
accepted:
27
10
2020
entrez:
16
12
2020
pubmed:
17
12
2020
medline:
17
12
2020
Statut:
epublish
Résumé
The sulfur(VI) fluoride exchange (SuFEx) reaction is an emerging scheme for connecting molecular building blocks. Due to its broad functional group tolerance and rather stable resulting linkage, it is seeing rapid adoption in various fields of chemistry. Still, to date the reaction mechanism is poorly understood, which hampers further development. Here, we show that the mechanism of the SuFEx reaction for the prototypical example of methanesulfonyl fluoride reacting with methylamine can be understood as an S
Identifiants
pubmed: 33324855
doi: 10.1021/acsomega.0c05049
pmc: PMC7726939
doi:
Types de publication
Journal Article
Langues
eng
Pagination
31432-31439Informations de copyright
© 2020 American Chemical Society.
Déclaration de conflit d'intérêts
The authors declare no competing financial interest.
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