Identifying Volatile Chemical Product Tracer Compounds in U.S. Cities.

With traffic emissions of volatile organic compounds (VOCs) decreasing rapidly over the last decades, the contributions of the emissions from other source categories, such as volatile chemical products (VCPs), have become more apparent in urban air. In this work, in situ measurements of various VOCs are reported for New York City, Pittsburgh, Chicago, and Denver. The magnitude of different emission sources relative to traffic is determined by measuring the urban enhancement of individual compounds relative to the enhancement of benzene, a known tracer of fossil fuel in the United States. The enhancement ratios of several VCP compounds to benzene correlate well with population density (