Synthesis of Tricyclic Laddersiloxane with Various Ring Sizes (Bat Siloxane).

hybrid organic-inorganic laddersiloxane silsesquioxane tricyclic laddersiloxane

Journal

Macromolecular rapid communications
ISSN: 1521-3927
Titre abrégé: Macromol Rapid Commun
Pays: Germany
ID NLM: 9888239

Informations de publication

Date de publication:
Mar 2021
Historique:
received: 14 10 2020
revised: 17 11 2020
pubmed: 17 12 2020
medline: 22 6 2021
entrez: 16 12 2020
Statut: ppublish

Résumé

A new synthetic method for tricyclic laddersiloxanes, ladder-type silsesquioxanes with defined structures, is developed based on intramolecular cyclization of hydrosilyl-functionalized cyclic siloxanes. This method enables the construction of unprecedented laddersiloxanes with various ring sizes. Herein, the preparation of tricyclic laddersiloxanes containing 6-8-6-, 8-8-8-, or 12-8-12-membered-ring systems is reported. These products can be considered as bat-shape siloxanes, owing to their rigid inorganic siloxane body with flexible oligosiloxane "wings" as side rings. The synthesized compounds are potential building blocks for well-defined nanomaterials, porous materials, and host molecules.

Identifiants

pubmed: 33326166
doi: 10.1002/marc.202000608
doi:

Substances chimiques

Siloxanes 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e2000608

Subventions

Organisme : New Energy and Industrial Technology Development Organization

Informations de copyright

© 2020 Wiley-VCH GmbH.

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Auteurs

Thanawat Chaiprasert (T)

Department of Chemistry and Chemical Biology, Graduate School of Science and Technology, Gunma University, Kiryu, 376-8515, Japan.

Yujia Liu (Y)

Department of Chemistry and Chemical Biology, Graduate School of Science and Technology, Gunma University, Kiryu, 376-8515, Japan.

Pa-Kwan Intaraprecha (PK)

Department of Chemistry and Chemical Biology, Graduate School of Science and Technology, Gunma University, Kiryu, 376-8515, Japan.

Rungthip Kunthom (R)

Department of Chemistry and Chemical Biology, Graduate School of Science and Technology, Gunma University, Kiryu, 376-8515, Japan.

Nobuhiro Takeda (N)

Department of Chemistry and Chemical Biology, Graduate School of Science and Technology, Gunma University, Kiryu, 376-8515, Japan.

Masafumi Unno (M)

Department of Chemistry and Chemical Biology, Graduate School of Science and Technology, Gunma University, Kiryu, 376-8515, Japan.

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