Acid-promoted hydride transfer from an NADH analogue to a Cr(iii)-superoxo complex via a proton-coupled hydrogen atom transfer.
Journal
Dalton transactions (Cambridge, England : 2003)
ISSN: 1477-9234
Titre abrégé: Dalton Trans
Pays: England
ID NLM: 101176026
Informations de publication
Date de publication:
14 Jan 2021
14 Jan 2021
Historique:
pubmed:
18
12
2020
medline:
23
9
2021
entrez:
17
12
2020
Statut:
ppublish
Résumé
The sequential transfer of an electron, a proton and an electron in a hydride transfer from dihydronicotinamide adenine dinucleotide (NADH) and its analogues has never been separated well. In addition, the effect of acids on hydride transfer from an NADH analogue to a metal-superoxo species has yet to be reported. We report herein the first example of an acid-promoted hydride transfer from an NADH analogue, 10-methyl-9,10-dihydroacridine (AcrH
Substances chimiques
Acridines
0
Coordination Complexes
0
Protons
0
Chromium
0R0008Q3JB
NAD
0U46U6E8UK
N-methylacridine
13367-81-2
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM