Determination of testosterone in serum and saliva by liquid chromatography-tandem mass spectrometry: An accurate and sensitive method applied on clinical and forensic samples.


Journal

Journal of pharmaceutical and biomedical analysis
ISSN: 1873-264X
Titre abrégé: J Pharm Biomed Anal
Pays: England
ID NLM: 8309336

Informations de publication

Date de publication:
20 Feb 2021
Historique:
received: 01 08 2020
revised: 23 11 2020
accepted: 30 11 2020
pubmed: 23 12 2020
medline: 22 6 2021
entrez: 22 12 2020
Statut: ppublish

Résumé

A highly sensitive and accurate electrospray liquid chromatography tandem-mass spectrometry (ESI-LC-MS/MS) method for determination of testosterone in human serum and saliva was developed and validated. Accurate quantification of testosterone in human matrices is essential in diagnosis and management of androgen status in men, women and children, and in forensic investigations of suspected abuse of anabolic androgenic steroids. Chromatography was performed on an HSS-T3 C18 column with a total run-time of 5.5 min. The tandem mass spectrometry was operated in positive electrospray ionization mode with multiple reaction monitoring. Serum and saliva samples of 200 μL, were prepared by solid-phase extraction using a 96-well plate following precipitation with 200 μL methanol.

Identifiants

pubmed: 33349473
pii: S0731-7085(20)31709-X
doi: 10.1016/j.jpba.2020.113823
pii:
doi:

Substances chimiques

Testosterone 3XMK78S47O

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

113823

Informations de copyright

Copyright © 2020 Elsevier B.V. All rights reserved.

Déclaration de conflit d'intérêts

Declaration of competing interest No competing interest is declared for all authors.

Auteurs

Yvonne Lood (Y)

National Board of Forensic Medicine, Department of Forensic Genetics and Forensic Toxicology, Linköping, Sweden; Department of Biomedical and Clinical Sciences, Linköping University, Linköping, Sweden. Electronic address: yvonne.lood@rmv.se.

Elisabeth Aardal (E)

Division of Clinical Chemistry and Department of Biomedical and Clinical Sciences, Linköping University, Linköping, Sweden.

Johan Ahlner (J)

Department of Biomedical and Clinical Sciences, Linköping University, Linköping, Sweden.

Andreas Ärlemalm (A)

Department of Clinical Pharmacology and Department of Biomedical and Clinical Sciences, Linköping University, Linköping, Sweden.

Björn Carlsson (B)

Department of Clinical Pharmacology and Department of Biomedical and Clinical Sciences, Linköping University, Linköping, Sweden.

Bertil Ekman (B)

Department of Endocrinology and Department of Health, Medicine and Caring Sciences, Linköping University, Linköping, Sweden.

Jeanette Wahlberg (J)

Department of Endocrinology and Department of Health, Medicine and Caring Sciences, Linköping University, Linköping, Sweden.

Martin Josefsson (M)

National Forensic Centre, Linköping, Sweden; Department of Physics, Chemistry and Biology, Linköping University, Linköping, Sweden.

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Classifications MeSH