Template-Mediated Control over Polymorphism in the Vapor-Assisted Formation of Zeolitic Imidazolate Framework Powders and Films.

chemical vapor deposition metal-organic frameworks physiosorption template synthesis thin films

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
29 Mar 2021
Historique:
revised: 18 12 2020
received: 04 11 2020
pubmed: 23 12 2020
medline: 23 12 2020
entrez: 22 12 2020
Statut: ppublish

Résumé

The landscape of possible polymorphs for some metal-organic frameworks (MOFs) can pose a challenge for controlling the outcome of their syntheses. Demonstrated here is the use of a template to control in the vapor-assisted formation of zeolitic imidazolate framework (ZIF) powders and thin films. Introducing a small amount of either ethanol or dimethylformamide vapor during the reaction between ZnO and 4,5-dichloroimidazole vapor results in the formation of the porous ZIF-71 phase, whereas other conditions lead to the formation of the dense ZIF-72 phase or amorphous materials. Time-resolved in situ small-angle X-ray scattering reveals that the porous phase is metastable and can be transformed into its dense polymorph. This transformation is avoided through the introduction of template vapor. The porosity of the resulting ZIF powders and films was studied by N

Identifiants

pubmed: 33350565
doi: 10.1002/anie.202014791
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

7553-7558

Subventions

Organisme : H2020 European Research Council
ID : 716472
Organisme : Fonds Wetenschappelijk Onderzoek
ID : G0E639N
Organisme : Fonds Wetenschappelijk Onderzoek
ID : G083016N
Organisme : Fonds Wetenschappelijk Onderzoek
ID : 1501618N
Organisme : Fonds Wetenschappelijk Onderzoek
ID : G0H0716N
Organisme : Fonds Wetenschappelijk Onderzoek
ID : 196025/12Z6520N
Organisme : Fonds Wetenschappelijk Onderzoek
ID : 1S00917N
Organisme : Fonds Wetenschappelijk Onderzoek
ID : 1S53316N
Organisme : KU Leuven
ID : C32/18/056
Organisme : H2020 Marie Skłodowska-Curie Actions
ID : 765378
Organisme : EU's H2020 framework programme
ID : 654360

Informations de copyright

© 2020 Wiley-VCH GmbH.

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Auteurs

Min Tu (M)

Centre for Membrane Separations, Adsorption, Catalysis, and Spectroscopy (cMACS), KU Leuven-University of Leuven, Celestijnenlaan 200F, 3001, Leuven, Belgium.

Dmitry E Kravchenko (DE)

Centre for Membrane Separations, Adsorption, Catalysis, and Spectroscopy (cMACS), KU Leuven-University of Leuven, Celestijnenlaan 200F, 3001, Leuven, Belgium.

Benzheng Xia (B)

Centre for Membrane Separations, Adsorption, Catalysis, and Spectroscopy (cMACS), KU Leuven-University of Leuven, Celestijnenlaan 200F, 3001, Leuven, Belgium.

Víctor Rubio-Giménez (V)

Centre for Membrane Separations, Adsorption, Catalysis, and Spectroscopy (cMACS), KU Leuven-University of Leuven, Celestijnenlaan 200F, 3001, Leuven, Belgium.

Nathalie Wauteraerts (N)

Centre for Membrane Separations, Adsorption, Catalysis, and Spectroscopy (cMACS), KU Leuven-University of Leuven, Celestijnenlaan 200F, 3001, Leuven, Belgium.

Rhea Verbeke (R)

Centre for Membrane Separations, Adsorption, Catalysis, and Spectroscopy (cMACS), KU Leuven-University of Leuven, Celestijnenlaan 200F, 3001, Leuven, Belgium.

Ivo F J Vankelecom (IFJ)

Centre for Membrane Separations, Adsorption, Catalysis, and Spectroscopy (cMACS), KU Leuven-University of Leuven, Celestijnenlaan 200F, 3001, Leuven, Belgium.

Timothée Stassin (T)

Centre for Membrane Separations, Adsorption, Catalysis, and Spectroscopy (cMACS), KU Leuven-University of Leuven, Celestijnenlaan 200F, 3001, Leuven, Belgium.

Werner Egger (W)

Department Institut für Angewandte Physik und Messtechnik LRT2, Universität der Bundeswehr München, Werner-Heisenberg-Weg 39, 85577, Neubiberg, Germany.

Marcel Dickmann (M)

Department Institut für Angewandte Physik und Messtechnik LRT2, Universität der Bundeswehr München, Werner-Heisenberg-Weg 39, 85577, Neubiberg, Germany.
Heinz Maier-Leibnitz Zentrum (MLZ), Technische Universität München, Lichtenbergstraße 1, 85748, Garching, Germany.

Heinz Amenitsch (H)

Institute of Inorganic Chemistry, Graz University of Technology, Stremayrgasse 9/IV, 8010, Graz, Austria.

Rob Ameloot (R)

Centre for Membrane Separations, Adsorption, Catalysis, and Spectroscopy (cMACS), KU Leuven-University of Leuven, Celestijnenlaan 200F, 3001, Leuven, Belgium.

Classifications MeSH