Inhomogeneous surface tension of chemically active fluid interfaces.
Journal
The Journal of chemical physics
ISSN: 1089-7690
Titre abrégé: J Chem Phys
Pays: United States
ID NLM: 0375360
Informations de publication
Date de publication:
21 Dec 2020
21 Dec 2020
Historique:
entrez:
23
12
2020
pubmed:
24
12
2020
medline:
24
12
2020
Statut:
ppublish
Résumé
We study the dependence of the surface tension of a fluid interface on the density profile of a third suspended phase. By means of an approximated model for the binary mixture and of a perturbative approach, we derive closed-form expressions for the free energy of the system and for the surface tension of the interface. Our results show a remarkable non-monotonous dependence of the surface tension on the spatial separation between the peaks of the density of the suspended phase. Our results also predict the local value of the surface tension in the case in which the density of the suspended phase is not homogeneous along the interface.
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM