Inhomogeneous surface tension of chemically active fluid interfaces.


Journal

The Journal of chemical physics
ISSN: 1089-7690
Titre abrégé: J Chem Phys
Pays: United States
ID NLM: 0375360

Informations de publication

Date de publication:
21 Dec 2020
Historique:
entrez: 23 12 2020
pubmed: 24 12 2020
medline: 24 12 2020
Statut: ppublish

Résumé

We study the dependence of the surface tension of a fluid interface on the density profile of a third suspended phase. By means of an approximated model for the binary mixture and of a perturbative approach, we derive closed-form expressions for the free energy of the system and for the surface tension of the interface. Our results show a remarkable non-monotonous dependence of the surface tension on the spatial separation between the peaks of the density of the suspended phase. Our results also predict the local value of the surface tension in the case in which the density of the suspended phase is not homogeneous along the interface.

Identifiants

pubmed: 33353340
doi: 10.1063/5.0025989
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

234903

Auteurs

Alessio Squarcini (A)

Max-Planck-Institut für Intelligente Systeme, Heisenbergstr. 3, D-70569 Stuttgart, Germany.

Paolo Malgaretti (P)

Max-Planck-Institut für Intelligente Systeme, Heisenbergstr. 3, D-70569 Stuttgart, Germany.

Classifications MeSH