Comments on "Molecular Chirality in Classical Spacetime: Solving the Controversy about the Spinning Cone Model of Rotating Molecules".
absolute enantioselection
chirality
optical rotation
parity and time reversal
spinning cone model
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
18 Jan 2021
18 Jan 2021
Historique:
received:
25
01
2020
pubmed:
29
12
2020
medline:
29
12
2020
entrez:
28
12
2020
Statut:
ppublish
Résumé
A recent mathematical analysis by Michel Petijean aimed at solving the Barron/Mislow controversy concerning the chirality or otherwise of a non-translating spinning cone concluded that both are right: the controversy is a matter of an arbitrary choice of a conversion factor. This reassessment highlights the different physicochemical properties of a stationary spinning cone and a chiral molecule and concludes that Petitjean's analysis is misleading.
Identifiants
pubmed: 33355960
doi: 10.1002/chem.202000427
doi:
Types de publication
Letter
Langues
eng
Sous-ensembles de citation
IM
Pagination
1476-1477Informations de copyright
© 2020 Wiley-VCH GmbH.
Références
M. Petitjean, Chem. Eur. J. 2020, 26, 10648-10652.
K. Mislow, Topics in Stereochemistry, Vol. 22 (Ed.: S. E. Denmark), Wiley, New York, 1999, pp. 1-82.
L. D. Barron, Molecular Light Scattering and Optical Activity, 2nd ed., Cambridge University Press, Cambridge, 2004, pp. 41, 204;
L. D. Barron in Chirality at the Nanoscale, Ed. D. B. Amabilano, Wiley-VCH, Weinheim, 2009, 1-27;
L. D. Barron, Rend. Fis. Acc. Lincei 2013, 24, 179-189.
L. D. Barron, Chem. Phys. Lett. 1981, 79, 392-394;
L. D. Barron, Mol. Phys. 1981, 43, 1395-1406;
L. D. Barron, Chem. Soc. Rev. 1986, 15, 189-223;
L. D. Barron, Chem. Phys. Lett. 1986, 123, 423-427;
L. D. Barron, J. Am. Chem. Soc. 1986, 108, 5539-5542.
J. Jonas, Chem. Papers 1997, 51, 167-182.
M. Avalos, R. Babiano, P. Cintas, J. L. Jiménez, J. C. Palacios, L. D. Barron, Chem. Rev. 1998, 98, 2391-2404.
L. D. Barron, Magnetochem. 2020, 6, 5;
N. Micali, H. Engelkamp, P. G. van Rhee, P. C. M. Christianen, L. Monsù. Scolaro, J. C. Maan, Nat. Chem. 2012, 4, 201-207;
K. Banerjee-Ghosh, O. Ben Dor, F. Tassinari, E. Capua, S. Yochelis, A. Capua, S.-H. Yang, S. S. P. Parkin, S. Sarkar, L. Kronik, L. T. Baczewski, R. Naaman, Y. Paltiel, Science 2018, 360, 1331-1334.