Efficient Separation of Acetylene and Carbon Dioxide in a Decorated Zeolite.
acetylene
gas separation
neutron diffraction
neutron scattering
zeolites
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
15 Mar 2021
15 Mar 2021
Historique:
received:
02
11
2020
revised:
11
12
2020
pubmed:
29
12
2020
medline:
29
12
2020
entrez:
28
12
2020
Statut:
ppublish
Résumé
The almost identical molecular sizes and volatilities of acetylene and carbon dioxide make their separation extremely challenging in industry. Reported here is the efficient separation of acetylene and carbon dioxide (v/v=2/1, which is relevant to that in the industrial cracking stream) in faujasite zeolites decorated with atomically-dispersed copper(II) sites under ambient conditions. In situ neutron powder diffraction and inelastic neutron scattering confirm that the confined copper(II) site displays chemoselective yet reversible binding to acetylene, whereas adsorbed carbon dioxide molecules are stabilized by weak host-guest supramolecular interactions with the framework oxygen centers, thus resulting in the efficient separation of these two gases under flow conditions. A designed adsorption-purging-desorption system based upon Cu@FAU is established for the recovery of high purity acetylene (98-99 %) from the mixture of acetylene and carbon dioxide, offering an unprecedented separation factor of 22.2 with an effective dynamic uptake of acetylene of 1.51 mmol g
Identifiants
pubmed: 33368904
doi: 10.1002/anie.202014680
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
6526-6532Subventions
Organisme : National Natural Science Foundation of China
ID : 22025203
Organisme : Municipal Natural Science Foundation of Tianjin
ID : 18JCJQJC47400
Organisme : The Royal Society
ID : NAF\R1\180297
Informations de copyright
© 2020 Wiley-VCH GmbH.
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