Double Porphyrin Cage Compounds.
Axial ligands
Host–guest chemistry
Porphyrin compounds
Journal
European journal of organic chemistry
ISSN: 1434-193X
Titre abrégé: European J Org Chem
Pays: Germany
ID NLM: 9805750
Informations de publication
Date de publication:
07 Dec 2020
07 Dec 2020
Historique:
received:
04
09
2020
entrez:
31
12
2020
pubmed:
1
1
2021
medline:
1
1
2021
Statut:
ppublish
Résumé
The synthesis and characterization of double porphyrin cage compounds are described. They consist of two porphyrins that are each attached to a diphenylglycoluril-based clip molecule via four ethyleneoxy spacers, and are linked together by a single alkyl chain using "click"-chemistry. Following a newly developed multistep synthesis procedure we report three of these double porphyrin cages, linked by spacers of different lengths, i.e. 3, 5, and 11 carbon atoms. The structures of the double porphyrin cages were fully characterized by NMR, which revealed that they consist of mixtures of two diastereoisomers. Their zinc derivatives are capable of forming sandwich-like complexes with the ditopic ligand 1,4-diazabicyclo[2,2,2]octane (
Identifiants
pubmed: 33380897
doi: 10.1002/ejoc.202001211
pii: EJOC202001211
pmc: PMC7756431
doi:
Types de publication
Journal Article
Langues
eng
Pagination
7087-7100Informations de copyright
© 2020 The Authors. European Journal of Organic Chemistry published by Wiley‐VCH GmbH.
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