Buried Interfaces in Halide Perovskite Photovoltaics.
buried interfaces
imperfections
microstructural reconstruction
perovskite photovoltaics
Journal
Advanced materials (Deerfield Beach, Fla.)
ISSN: 1521-4095
Titre abrégé: Adv Mater
Pays: Germany
ID NLM: 9885358
Informations de publication
Date de publication:
Feb 2021
Feb 2021
Historique:
received:
21
09
2020
revised:
15
11
2020
pubmed:
5
1
2021
medline:
5
1
2021
entrez:
4
1
2021
Statut:
ppublish
Résumé
Understanding the fundamental properties of buried interfaces in perovskite photovoltaics is of paramount importance to the enhancement of device efficiency and stability. Nevertheless, accessing buried interfaces poses a sizeable challenge because of their non-exposed feature. Herein, the mystery of the buried interface in full device stacks is deciphered by combining advanced in situ spectroscopy techniques with a facile lift-off strategy. By establishing the microstructure-property relations, the basic losses at the contact interfaces are systematically presented, and it is found that the buried interface losses induced by both the sub-microscale extended imperfections and lead-halide inhomogeneities are major roadblocks toward improvement of device performance. The losses can be considerably mitigated by the use of a passivation-molecule-assisted microstructural reconstruction, which unlocks the full potential for improving device performance. The findings open a new avenue to understanding performance losses and thus the design of new passivation strategies to remove imperfections at the top surfaces and buried interfaces of perovskite photovoltaics, resulting in substantial enhancement in device performance.
Identifiants
pubmed: 33393159
doi: 10.1002/adma.202006435
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2006435Subventions
Organisme : National Natural Science Foundation of China
ID : 61722501
Organisme : National Natural Science Foundation of China
ID : 91733301
Organisme : National Natural Science Foundation of China
ID : 62004165
Organisme : National Natural Science Foundation of China
ID : 11527901
Organisme : National Basic Research Program of China
ID : 2015CB932203
Organisme : EPSRC
ID : 2018;EP/R043272/1
Organisme : EPSRC
ID : EP/R023980/1
Organisme : Royal Society
Organisme : Tata Group
ID : UF150033
Organisme : National Natural Science Foundation of China
ID : 51602290
Organisme : Zhengzhou University
ID : XKZDJC201903
Organisme : European Union's Horizon 2020 research and innovation program
ID : 841386
Organisme : Office of Naval Research
ID : N00014-15-1-2244
Organisme : Office of Science
Organisme : Basic Energy Sciences
Organisme : U.S. Department of Energy
ID : DE-AC02-05CH11231
Organisme : Marie Skłodowska-Curie Individual Fellowships
ID : 839136
Organisme : China Postdoctoral Science Foundation
ID : 2018M633128
Organisme : Shenzhen Basic Research Project
ID : JCYJ20170818142926085
Informations de copyright
© 2021 Wiley-VCH GmbH.
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