HgH

X-ray constrained wavefunction charge density quantum crystallography relativistic effects scaling

Journal

Acta crystallographica. Section A, Foundations and advances
ISSN: 2053-2733
Titre abrégé: Acta Crystallogr A Found Adv
Pays: United States
ID NLM: 101620182

Informations de publication

Date de publication:
01 Jan 2021
Historique:
received: 30 06 2020
accepted: 09 11 2020
entrez: 5 1 2021
pubmed: 6 1 2021
medline: 6 1 2021
Statut: ppublish

Résumé

The capability of X-ray constrained wavefunction (XCW) fitting to introduce relativistic effects into a non-relativistic wavefunction is tested. It is quantified how much of the reference relativistic effects can be absorbed in the non-relativistic XCW calculation when fitted against relativistic structure factors of a model HgH

Identifiants

pubmed: 33399131
pii: S2053273320014837
doi: 10.1107/S2053273320014837
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

54-66

Subventions

Organisme : Agentúra na Podporu Výskumu a Vývoja
ID : APVV-15-0079
Organisme : Agentúra na Podporu Výskumu a Vývoja
ID : APVV-19-0087
Organisme : Vedecká Grantová Agentúra MŠVVaŠ SR a SAV
ID : 1/0719/19
Organisme : Vedecká Grantová Agentúra MŠVVaŠ SR a SAV
ID : 1/0139/20

Auteurs

Michal Podhorský (M)

Institute of Physical Chemistry and Chemical Physics FCHPT, Slovak University of Technology, Radlinskeho 9, Bratislava SK-812 37, Slovakia.

Lukáš Bučinský (L)

Institute of Physical Chemistry and Chemical Physics FCHPT, Slovak University of Technology, Radlinskeho 9, Bratislava SK-812 37, Slovakia.

Dylan Jayatilaka (D)

School of Molecular Sciences, The University of Western Australia, 35 Stirling Hwy, Perth WA 6009, Australia.

Simon Grabowsky (S)

Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, 3012 Bern, Switzerland.

Classifications MeSH