Groundwater quality trend and trend reversal assessment in the European Water Framework Directive context: an example with nitrates in Italy.

Ground Water Directive Groundwater chemical status Mann-Kendall Nitrate pollution Pettitt test River Basin Management Plans

Journal

Environmental science and pollution research international
ISSN: 1614-7499
Titre abrégé: Environ Sci Pollut Res Int
Pays: Germany
ID NLM: 9441769

Informations de publication

Date de publication:
May 2021
Historique:
received: 16 05 2020
accepted: 07 12 2020
pubmed: 8 1 2021
medline: 13 5 2021
entrez: 7 1 2021
Statut: ppublish

Résumé

Groundwater resources are of utmost importance in sustaining water related ecosystems, including humans. The long-lasting impacts from anthropogenic activities require early actions, owing to the natural time lag in groundwater formation and renewal. The European Union (EU) policy, within the implementation of the Water Framework Directive (WFD), requires Member States to identify and reverse any significant and sustained upward trend in the concentration of pollutants, defining specific protection measures to be included in the River Basin Management Plans (RBMP). In Italy, official guidelines for trend and trend reversal assessment have been published recently. Statistical methods, such as the Mann-Kendall test for trend analysis and the Sen's method for estimating concentration scenarios, should be applied at the fixed terms stated by the WFD implementation cycles to identify upward trends, while the Pettitt test is proposed for the identification of trend reversal. In this paper, we present an application of a slightly modified version of the Italian Guidelines to a groundwater body in Northern Italy featuring nitrate pollution and discuss its advantages and limitations. In addition to Pettitt test, for the trend reversal analysis, we apply the Mann-Kendall test in two sections and compare the results. We conclude that this method seems more reliable than Pettitt test to identify a reversal point in quality time series. The overall procedure can be easily applied to any groundwater body defined at risk across Europe, for the assessment of the upward trends of pollutants and their reversal, even with little chemical monitoring data. Although focused on the EU legislative framework, this procedure may be relevant for a wider context, allowing to individuate upward trend as early warning for contamination processes in an integrated water resources management context.

Identifiants

pubmed: 33411302
doi: 10.1007/s11356-020-11998-0
pii: 10.1007/s11356-020-11998-0
pmc: PMC8106612
doi:

Substances chimiques

Nitrates 0
Water Pollutants, Chemical 0
Water 059QF0KO0R

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

22092-22104

Références

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Auteurs

Eleonora Frollini (E)

IRSA-CNR, Via Salaria km 29,300, 00015, Monterotondo, Roma, Italy.

Elisabetta Preziosi (E)

IRSA-CNR, Via Salaria km 29,300, 00015, Monterotondo, Roma, Italy. elisabetta.preziosi@cnr.it.

Nicoletta Calace (N)

ISPRA, Via Vitaliano Brancati, 48, 00144, Rome, Italy.

Maurizio Guerra (M)

ISPRA, Via Vitaliano Brancati, 48, 00144, Rome, Italy.

Nicolas Guyennon (N)

IRSA-CNR, Via Salaria km 29,300, 00015, Monterotondo, Roma, Italy.

Marco Marcaccio (M)

ARPAE Emilia Romagna, Largo Caduti del Lavoro, 6, 40122, Bologna, Italy.

Stefano Menichetti (S)

ARPAT Toscana, Via N. Porpora, 22, 50144, Firenze, Italy.

Emanuele Romano (E)

IRSA-CNR, Via Salaria km 29,300, 00015, Monterotondo, Roma, Italy.

Stefano Ghergo (S)

IRSA-CNR, Via Salaria km 29,300, 00015, Monterotondo, Roma, Italy.

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