A Patternable and In Situ Formed Polymeric Zinc Blanket for a Reversible Zinc Anode in a Skin-Mountable Microbattery.
Zn anodes
Zn-ion coordination
microbatteries
patternable polymers
wearables
Journal
Advanced materials (Deerfield Beach, Fla.)
ISSN: 1521-4095
Titre abrégé: Adv Mater
Pays: Germany
ID NLM: 9885358
Informations de publication
Date de publication:
Feb 2021
Feb 2021
Historique:
received:
02
11
2020
revised:
30
11
2020
pubmed:
16
1
2021
medline:
16
1
2021
entrez:
15
1
2021
Statut:
ppublish
Résumé
Owing to their high safety and reversibility, aqueous microbatteries using zinc anodes and an acid electrolyte have emerged as promising candidates for wearable electronics. However, a critical limitation that prevents implementing zinc chemistry at the microscale lies in its spontaneous corrosion in an acidic electrolyte that causes a capacity loss of 40% after a ten-hour rest. Widespread anti-corrosion techniques, such as polymer coating, often retard the kinetics of zinc plating/stripping and lack spatial control at the microscale. Here, a polyimide coating that resolves this dilemma is reported. The coating prevents corrosion and hence reduces the capacity loss of a standby microbattery to 10%. The coordination of carbonyl oxygen in the polyimide with zinc ions builds up over cycling, creating a zinc blanket that minimizes the concentration gradient through the electrode/electrolyte interface and thus allows for fast kinetics and low plating/stripping overpotential. The polyimide's patternable feature energizes microbatteries in both aqueous and hydrogel electrolytes, delivering a supercapacitor-level rate performance and 400 stable cycles in the hydrogel electrolyte. Moreover, the microbattery is able to be attached to human skin and offers strong resistance to deformations, splashing, and external shock. The skin-mountable microbattery demonstrates an excellent combination of anti-corrosion, reversibility, and durability in wearables.
Identifiants
pubmed: 33448064
doi: 10.1002/adma.202007497
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2007497Subventions
Organisme : China Scholarship Council
Organisme : National Natural Science Foundation of China
ID : 11904153
Organisme : German Research Foundation
Organisme : SPP 1857 ESSENCE
ID : KA5051/1-1
Organisme : Leibniz Program of the German Research Foundation
ID : SCHM 1298/26-1
Organisme : Young Scientists Fund
ID : 11904153
Informations de copyright
© 2021 The Authors. Advanced Materials published by Wiley-VCH GmbH.
Références
J. Y. Oh, Z. Bao, Adv. Sci. 2019, 6, 1900186.
M. Mehrali, S. Bagherifard, M. Akbari, A. Thakur, B. Mirani, M. Mehrali, M. Hasany, G. Orive, P. Das, J. Emneus, T. L. Andresen, A. Dolatshahi-Pirouz, Adv. Sci. 2018, 5, 1700931.
Y. Liu, M. Pharr, G. A. Salvatore, ACS Nano 2017, 11, 9614.
C. García Núñez, L. Manjakkal, R. Dahiya, npj Flexible Electron. 2019, 3, 1.
A. J. Bandodkar, P. Gutruf, J. Choi, K. H. Lee, Y. Sekine, J. T. Reeder, W. J. Jeang, A. J. Aranyosi, S. P. Lee, J. B. Model, R. Ghaffari, C. J. Su, J. P. Leshock, T. Ray, A. Verrillo, K. Thomas, V. Krishnamurthi, S. Han, J. Kim, S. Krishnan, T. Hang, J. A. Rogers, Sci. Adv. 2019, 5, eaav3294.
T. Someya, Z. Bao, G. G. Malliaras, Nature 2016, 540, 379.
D. Jiang, B. Shi, H. Ouyang, Y. Fan, Z. L. Wang, Z. Li, ACS Nano 2020, 14, 6436..
S. Zheng, X. Shi, P. Das, Z. S. Wu, X. Bao, Adv. Mater. 2019, 31, 1900583.
N. A. Kyeremateng, T. Brousse, D. Pech, Nat. Nanotechnol. 2017, 12, 7.
J. Ryu, M. Park, J. Cho, Adv. Mater. 2019, 31, 1804784.
G. Liang, F. Mo, X. Ji, C. Zhi, Nat. Rev. Mater. 2020, https://doi.org/10.1038/s41578-020-00241-4.
B. Tang, L. Shan, S. Liang, J. Zhou, Energy Environ. Sci. 2019, 12, 3288.
G. Fang, J. Zhou, A. Pan, S. Liang, ACS Energy Lett. 2018, 3, 2480.
A. Konarov, N. Voronina, J. H. Jo, Z. Bakenov, Y. K. Sun, S. T. Myung, ACS Energy Lett. 2018, 3, 2620.
N. Zhang, X. Chen, M. Yu, Z. Niu, F. Cheng, J. Chen, Chem. Soc. Rev. 2020, 49, 4203.
Y. Jin, K. S. Han, Y. Shao, M. L. Sushko, J. Xiao, H. Pan, J. Liu, Adv. Funct. Mater. 2020, 30, 2003932.
H. Qiu, X. Du, J. Zhao, Y. Wang, J. Ju, Z. Chen, Z. Hu, D. Yan, X. Zhou, G. Cui, Nat. Commun. 2019, 10, 5374.
S. Higashi, S. W. Lee, J. S. Lee, K. Takechi, Y. Cui, Nat. Commun. 2016, 7, 11801.
Z. Zhao, J. Zhao, Z. Hu, J. Li, J. Li, Y. Zhang, C. Wang, G. Cui, Energy Environ. Sci. 2019, 12, 1938.
Y. Yin, O. Yamada, K. Tanaka, K. I. Okamoto, Polym. J. 2006, 38, 197.
J. Wang, V. K. Bandari, D. Karnaushenko, Y. Li, F. Li, P. Zhang, S. Baunack, D. D. Karnaushenko, C. Becker, M. Faghih, T. Kang, S. Duan, M. Zhu, X. Zhuang, F. Zhu, X. Feng, O. G. Schmidt, ACS Nano 2019, 13, 8067.
T. H. Muster, A. K. Neufeld, I. S. Cole, Corros. Sci. 2004, 46, 2337.
J. Peng, B. Chen, Z. Wang, J. Guo, B. Wu, S. Hao, Q. Zhang, L. Gu, Q. Zhou, Z. Liu, S. Hong, S. You, A. Fu, Z. Shi, H. Xie, D. Cao, C. Lin, G. Fu, L.-S. Zheng, Y. Jiang, N. Zheng, Nature 2020, 586, 390.
R. W. Snyder, B. Thomson, B. Bartges, D. Czerniawski, P. C. Painter, Macromolecules 1989, 22, 4166.
M. Chamoun, B. J. Hertzberg, T. Gupta, D. Davies, S. Bhadra, B. Van Tassell, C. Erdonmez, D. A. Steingart, NPG Asia Mater 2015, 7, e178.
E. McCafferty, in Introduction to Corrosion Science, Springer, New York 2010, pp. 403-425.
E. McCafferty, in Introduction to Corrosion Science, Springer, New York, 2010, pp. 427-451.
M. Doyle, T. F. Fuller, J. Newman, Electrochim. Acta 1994, 39, 2073.
E. Vallejo, G. Pourcelly, C. Gavach, R. Mercier, M. Pineri, J. Membr. Sci. 1999, 160, 127.
M. J. Baran, M. N. Braten, S. Sahu, A. Baskin, S. M. Meckler, L. Li, L. Maserati, M. E. Carrington, Y. M. Chiang, D. Prendergast, B. A. Helms, Joule 2019, 3, 2968.
R. Gracia, D. Mecerreyes, Polym. Chem. 2013, 4, 2206.
C. Mao, L. Fang, H. Zhang, W. Li, F. Wu, G. Qin, H. Ruan, C. Kong, J. Alloys Compd. 2016, 676, 135.
W. Li, L. Fang, G. Qin, H. Ruan, H. Zhang, C. Kong, L. Ye, P. Zhang, F. Wu, J. Appl. Phys. 2015, 117, 145301.
A. Cano, L. Lartundo-Rojas, A. Shchukarev, E. Reguera, New J. Chem. 2019, 43, 4835.
Y. J. Oh, J. J. Yoo, Y. Il Kim, J. K. Yoon, H. N. Yoon, J. H. Kim, S. Bin Park, Electrochim. Acta 2014, 116, 118.
L. Q. Wu, Y. C. Li, S. Q. Li, Z. Z. Li, G. D. Tang, W. H. Qi, L. C. Xue, X. S. Ge, L. L. Ding, AIP Adv. 2015, 5, 097210.
L. Chen, W. Li, Z. Guo, Y. Wang, C. Wang, Y. Che, Y. Xia, J. Electrochem. Soc. 2015, 162, A1972.
H. Yang, S. Liu, L. Cao, S. Jiang, H. Hou, J. Mater. Chem. A 2018, 6, 21216.
G. Deroubaix, P. Marcus, Surf. Interface Anal. 1992, 18, 39.
W. Sun, F. Wang, S. Hou, C. Yang, X. Fan, Z. Ma, T. Gao, F. Han, R. Hu, M. Zhu, C. Wang, J. Am. Chem. Soc. 2017, 139, 9775.
F. Wan, X. Zhou, Y. Lu, Z. Niu, J. Chen, ACS Energy Lett. 2020, 12, 3569.
T. Xue, H. J. Fan, J. Energy Chem. 2021, 54, 194.
X. Guo, J. Zhou, C. Bai, X. Li, G. Fang, S. Liang, Mater. Today Energy 2020, 16, 100396.
D. D. Karnaushenko, D. Karnaushenko, H. J. Grafe, V. Kataev, B. Büchner, O. G. Schmidt, Adv. Electron. Mater. 2018, 4, 1800298.
M. Zhu, Z. Wang, H. Li, Y. Xiong, Z. Liu, Z. Tang, Y. Huang, A. L. Rogach, C. Zhi, Energy Environ. Sci. 2018, 11, 2414.