Nuclearity and Host Effects of Carbon-Supported Platinum Catalysts for Dibromomethane Hydrodebromination.
carbon carriers
hydrodebromination
mechanism
nanoparticles
single atoms
speciation
Journal
Small (Weinheim an der Bergstrasse, Germany)
ISSN: 1613-6829
Titre abrégé: Small
Pays: Germany
ID NLM: 101235338
Informations de publication
Date de publication:
Apr 2021
Apr 2021
Historique:
revised:
13
11
2020
received:
25
08
2020
pubmed:
20
1
2021
medline:
20
1
2021
entrez:
19
1
2021
Statut:
ppublish
Résumé
The identification of the active sites and the derivation of structure-performance relationships are central for the development of high-performance heterogeneous catalysts. Here, a platform of platinum nanostructures, ranging from single atoms to nanoparticles of ≈4 nm supported on activated- and N-doped carbon (AC and NC), is employed to systematically assess nuclearity and host effects on the activity, selectivity, and stability in dibromomethane hydrodebromination, a key step in bromine-mediated methane functionalization processes. For this purpose, catalytic evaluation is coupled to in-depth characterization, kinetic analysis, and mechanistic studies based on density functional theory. Remarkably, the single atom catalysts achieve exceptional selectivity toward CH
Identifiants
pubmed: 33464715
doi: 10.1002/smll.202005234
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2005234Subventions
Organisme : Ministerio de Ciencia, Innovación y Universidades
ID : SEV-2013-0319
Organisme : Eidgenössische Technische Hochschule Zürich
ID : ETH-43 18-1
Organisme : Eidgenössische Technische Hochschule Zürich
ID : ETH-40 17-1
Informations de copyright
© 2021 Wiley-VCH GmbH.
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