Palladium-Catalyzed Difunctionalization of 1,3-Diene with Amine and Disilane under a Mild Re-oxidation System.
difunctionalization
molecular oxygen
oxidative amination
palladium
regio- and stereoselective
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
12 Mar 2021
12 Mar 2021
Historique:
received:
05
01
2021
revised:
19
01
2021
pubmed:
21
1
2021
medline:
21
1
2021
entrez:
20
1
2021
Statut:
ppublish
Résumé
A highly regioselective and stereoselective difunctionalization reaction of 1,3-diene with amine and disilane to form C-N and C-Si bonds via a one-step Pd/Cu/O
Identifiants
pubmed: 33470481
doi: 10.1002/chem.202100043
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
4888-4892Subventions
Organisme : New Energy and Industrial Technology Development Organization
ID : 14100355-0
Informations de copyright
© 2021 Wiley-VCH GmbH.
Références
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Related our patents, see:
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We conducted computational calculations of the Gibbs free energy (kcal mol−1) between Z and E isomers of 4 a at the M06-2X/6-311+G(d,p)//B3LYP/6-31+G(d,p) level of theory with Gaussian 16. All calculated data involve Gibbs energy using thermal corrections at 343 K with CPCM model (DMF solvent). The results showed that Z isomer is thermodynamically more stable than E isomer (see the Supporting Information).
For detailed reaction conditions, see the Supporting Information.
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Deposition Number 2044491 contains the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe Access Structures service www.ccdc.cam.ac.uk/structures.