Tuning the solid-state emission of liquid crystalline nitro-cyanostilbene by halogen bonding.

fluorescence halogen bonding liquid crystal

Journal

Beilstein journal of organic chemistry
ISSN: 1860-5397
Titre abrégé: Beilstein J Org Chem
Pays: Germany
ID NLM: 101250746

Informations de publication

Date de publication:
2021
Historique:
received: 23 10 2020
accepted: 17 12 2020
entrez: 1 2 2021
pubmed: 2 2 2021
medline: 2 2 2021
Statut: epublish

Résumé

The first example of halogen-bonded fluorescent liquid crystals based on the interaction of iodofluorobenzene derivatives with nitro-cyanostilbenes is reported. The systematic variation of the fluorination degree and pattern indicates the relevance of the halogen bond strength for the induction of liquid crystalline properties. The modular self-assembly approach enables the efficient tuning of the fluorescence behaviour and mesomorphic properties of the assemblies.

Identifiants

pubmed: 33519999
doi: 10.3762/bjoc.17.13
pmc: PMC7814182
doi:

Types de publication

Journal Article

Langues

eng

Pagination

124-131

Informations de copyright

Copyright © 2021, Nath et al.; licensee Beilstein-Institut.

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Auteurs

Subrata Nath (S)

Organic Chemistry, University of Duisburg Essen, Universitätsstraße 7, 45141 Essen, Germany.

Alexander Kappelt (A)

Organic Chemistry, University of Duisburg Essen, Universitätsstraße 7, 45141 Essen, Germany.

Matthias Spengler (M)

Organic Chemistry, University of Duisburg Essen, Universitätsstraße 7, 45141 Essen, Germany.

Bibhisan Roy (B)

Organic Chemistry, University of Duisburg Essen, Universitätsstraße 7, 45141 Essen, Germany.

Jens Voskuhl (J)

Organic Chemistry, University of Duisburg Essen, Universitätsstraße 7, 45141 Essen, Germany.

Michael Giese (M)

Organic Chemistry, University of Duisburg Essen, Universitätsstraße 7, 45141 Essen, Germany.

Classifications MeSH