The Synthesis and Characterisation of a Molecular Sea-Serpent: Studies of a {Cr
chromium
magnetic studies
spin chains
supramolecular
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
19 Apr 2021
19 Apr 2021
Historique:
received:
25
11
2020
pubmed:
13
2
2021
medline:
13
2
2021
entrez:
12
2
2021
Statut:
ppublish
Résumé
A finite chain of thirty-one paramagnetic centers is reported, synthesized by reaction of hydrated chromium fluoride, copper carbonate and pivalic acid in the presence of 1,4,7,10-tetrazacyclododecane (cyclen). Magnetic studies show predominantly anti-ferromagnetic exchange leading to a high density of low-lying spin states and large saturation field.
Identifiants
pubmed: 33576165
doi: 10.1002/anie.202015731
pmc: PMC8251705
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
9489-9492Subventions
Organisme : Engineering and Physical Sciences Research Council
ID : EP/R043701/1
Organisme : Engineering and Physical Sciences Research Council
ID : EP/R011079/1
Organisme : Engineering and Physical Sciences Research Council
ID : EP/S033181/1
Organisme : Engineering and Physical Sciences Research Council
ID : EP/K0395471/1
Organisme : Engineering and Physical Sciences Research Council
ID : NS/A000055/1
Organisme : H2020 European Research Council
ID : ERC-2017-ADG-786734
Informations de copyright
© 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
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