Direct observation of coherent femtosecond solvent reorganization coupled to intramolecular electron transfer.
Journal
Nature chemistry
ISSN: 1755-4349
Titre abrégé: Nat Chem
Pays: England
ID NLM: 101499734
Informations de publication
Date de publication:
04 2021
04 2021
Historique:
received:
12
06
2020
accepted:
14
12
2020
pubmed:
17
2
2021
medline:
17
2
2021
entrez:
16
2
2021
Statut:
ppublish
Résumé
It is well known that the solvent plays a critical role in ultrafast electron-transfer reactions. However, solvent reorganization occurs on multiple length scales, and selectively measuring short-range solute-solvent interactions at the atomic level with femtosecond time resolution remains a challenge. Here we report femtosecond X-ray scattering and emission measurements following photoinduced charge-transfer excitation in a mixed-valence bimetallic (Fe
Identifiants
pubmed: 33589787
doi: 10.1038/s41557-020-00629-3
pii: 10.1038/s41557-020-00629-3
doi:
Banques de données
figshare
['10.6084/m9.figshare.13322975']
Types de publication
Journal Article
Research Support, U.S. Gov't, Non-P.H.S.
Langues
eng
Sous-ensembles de citation
IM
Pagination
343-349Commentaires et corrections
Type : ErratumIn
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