Photochemistry of Tris(2,4-dibromophenyl)amine and its Application to Co-oxidation on Sulfides and Phosphines.
Journal
Photochemistry and photobiology
ISSN: 1751-1097
Titre abrégé: Photochem Photobiol
Pays: United States
ID NLM: 0376425
Informations de publication
Date de publication:
Nov 2021
Nov 2021
Historique:
revised:
09
02
2021
received:
05
01
2021
accepted:
15
02
2021
pubmed:
21
2
2021
medline:
21
2
2021
entrez:
20
2
2021
Statut:
ppublish
Résumé
The photochemistry of tris(2,4-dibromophenyl)amine was investigated via time-resolved nanosecond spectroscopy. The tris(2,4-dibromophenyl)amine radical cation ("Magic Green") was immediately detected after the laser pulse; this intermediate then cyclizes to N-aryl-4a,4b-dihydrocarbazole radical cation. The latter transient reacted with molecular oxygen to provide the corresponding hydroperoxyl radical, which smoothly co-oxidize sulfides into sulfoxides. On the other hand, the photogenerated "Magic Green" was exploited to promote the co-oxidation of nucleophilic triarylphosphines to triarylphosphine oxides through an electron transfer process preventing the amine cyclization. In this case, the intermediate Ar
Types de publication
Journal Article
Review
Langues
eng
Sous-ensembles de citation
IM
Pagination
1278-1288Informations de copyright
© 2021 American Society for Photobiology.
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