Rheo-optical Near-infrared (NIR) Analysis of Binary Amorphous Polymer Blend Consisting of Polyvinyl Chloride (PVC) and Polymethyl Methacrylate (PMMA).

Near-infrared spectroscopy polymer blend polymethyl methacrylate polyvinyl chloride two-trace two-dimensional correlation spectroscopy

Journal

Analytical sciences : the international journal of the Japan Society for Analytical Chemistry
ISSN: 1348-2246
Titre abrégé: Anal Sci
Pays: Switzerland
ID NLM: 8511078

Informations de publication

Date de publication:
10 Sep 2021
Historique:
pubmed: 23 2 2021
medline: 23 2 2021
entrez: 22 2 2021
Statut: ppublish

Résumé

A binary amorphous polymer blend consisting of polyvinyl chloride (PVC) and polymethyl methacrylate (PMMA) was studied with a rheo-optical characterization technique based on the combination of a near-infrared (NIR) spectrometer and a tensile testing machine. In rheo-optical NIR spectroscopy, tensile deformations were applied to polymers to induce the displacement of molecular chains while being probed by NIR light. The application of this technique was extended to a partially miscible amorphous polymer blend consisting of PVC and PMMA to demonstrate how it can be utilized to detect subtle but important deformation behavior. A change in the NIR spectral feature revealed that the initial deformation of the blend induces the reorientation of the PVC chains. A part of the PMMA connected to the PVC was tagged during the PVC deformation. Further deformation of the sample eventually resulted in necking propagation to the surrounding area.

Identifiants

DOI: 10.2116/analsci.21P004 PMID: 33612560
pubmed: 33612560
doi: 10.2116/analsci.21P004
pii: 10.2116/analsci.21P004
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

1259-1264

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Auteurs

Maito Koga (M)

Research Institute for Sustainable Chemistry, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, 305-8565, Japan.

Ryota Watanabe (R)

Research Institute for Sustainable Chemistry, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, 305-8565, Japan.

Junji Mizukado (J)

Research Institute for Sustainable Chemistry, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, 305-8565, Japan.

Hideyuki Shinzawa (H)

Research Institute for Sustainable Chemistry, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, 305-8565, Japan. h-shinzawa@aist.go.jp.

Classifications MeSH