Multinuclear Ag Clusters Sandwiched by Pt Complex Units: Fluxional Behavior and Chiral-at-Cluster Photoluminescence.
Ag cluster
Pt complex
fluxional behavior
photoluminescence
sandwich complex
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
03 May 2021
03 May 2021
Historique:
received:
30
01
2021
pubmed:
23
2
2021
medline:
23
2
2021
entrez:
22
2
2021
Statut:
ppublish
Résumé
Multinuclear Ag clusters sandwiched by Pt complex units were synthesized and characterized by single crystal X-ray diffraction and NMR studies. The sandwich-shaped multinuclear Ag complexes showed two different types of fluxional behavior in solution: rapid slippage of Pt complex units on the Ag
Identifiants
pubmed: 33617126
doi: 10.1002/anie.202101460
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
10654-10660Subventions
Organisme : Japan Society for the Promotion of Science
ID : JP16H0659
Organisme : Japan Society for the Promotion of Science
ID : JP19K15589
Organisme : Japan Society for the Promotion of Science
ID : JP19H04587
Organisme : Japan Society for the Promotion of Science
ID : JP20K05542
Organisme : Japan Society for the Promotion of Science
ID : JP20H05231
Organisme : Japan Society for the Promotion of Science
ID : JPMXS0422500320
Organisme : Izumi Science and Technology Foundation
ID : 2020-J-012
Organisme : Deutsche Forschungsgemeinschaft
ID : EXC 2033-390677874
Informations de copyright
© 2021 Wiley-VCH GmbH.
Références
T. Murahashi, M. Fujimoto, M. Oka, Y. Hashimoto, T. Uemura, Y. Tatsumi, Y. Nakao, A. Ikeda, S. Sakaki, H. Kurosawa, Science 2006, 313, 1104-1107;
T. Murahashi, R. Inoue, K. Usui, S. Ogoshi, J. Am. Chem. Soc. 2009, 131, 9888-9889;
T. Murahashi, K. Shirato, A. Fukushima, K. Takase, T. Suenobu, S. Fukuzumi, S. Ogoshi, H. Kurosawa, Nat. Chem. 2012, 4, 52-58;
T. Murahashi, K. Usui, R. Inoue, S. Ogoshi, H. Kurosawa, Chem. Sci. 2011, 2, 117-122;
S. Horiuchi, Y. Tachibana, M. Yamashita, K. Yamamoto, K. Masai, K. Takase, T. Matsutani, S. Kawamata, Y. Kurashige, T. Yanai, T. Murahashi, Nat. Commun. 2015, 6, 6742;
K. Masai, K. Shirato, K. Yamamoto, Y. Kurashige, T. Murahashi, Chem. Commun. 2016, 52, 6427-6430;
Y. Ishikawa, K. Yamamoto, T. Murahashi, Angew. Chem. Int. Ed. 2017, 56, 1346-1350;
Angew. Chem. 2017, 129, 1366-1370;
M. Teramoto, K. Iwata, H. Yamaura, K. Kurashima, K. Miyazawa, Y. Kurashige, K. Yamamoto, T. Murahashi, J. Am. Chem. Soc. 2018, 140, 12682-12686;
M. Yamashita, Y. Kawasumi, Y. Tachibana, S. Horiuchi, K. Yamamoto, T. Murahashi, Chem. Eur. J. 2019, 25, 1212-1216;
M. Yamashita, S. Horiuchi, K. Yamamoto, T. Murahashi, Dalton Trans. 2019, 48, 13149-13153;
T. Ishikawa, A. Kawamura, T. Sugawa, R. Moridaira, K. Yamamoto, T. Murahashi, Angew. Chem. Int. Ed. 2019, 58, 15318-15323;
Angew. Chem. 2019, 131, 15462-15467;
L.-J. Wang, X. Li, S. Bai, Y.-Y. Wang, Y.-F. Han, J. Am. Chem. Soc. 2020, 142, 2524-2531.
F.-X. Pan, L.-J. Li, Y.-J. Wang, J.-C. Guo, H.-J. Zhai, L. Xu, Z.-M. Sun, J. Am. Chem. Soc. 2015, 137, 10954-10957.
For selected reviews of metallophilic interactions, see:
H. Schmidbaur, A. Schier, Chem. Soc. Rev. 2012, 41, 370-412;
H. Schmidbaur, A. Schier, Angew. Chem. Int. Ed. 2015, 54, 746-784;
Angew. Chem. 2015, 127, 756-797;
N. V. S. Harisomayajula, S. Makovetskyi, Y.-C. Tsai, Chem. Eur. J. 2019, 25, 8936-8954.
For selected reviews of triangular M3 complexes, see:
K. Fujisawa, Y. Ishikawa, Y. Miyashita, K. Okamoto, Inorg. Chim. Acta 2010, 363, 2977-2989;
Y. Morishima, D. J. Young, K. Fujisawa, Dalton Trans. 2014, 43, 15915-15928;
J. Zheng, Z. Lu, K. Wu, G.-H. Ning, D. Li, Chem. Rev. 2020, 120, 9675-9742.
M. A. Omary, A. A. Mohamed, M. A. Rawashdeh-Omary, J. P. Fackler, Jr., Coord. Chem. Rev. 2005, 249, 1372-1381;
M. A. Omary, M. A. Rawashdeh-Omary, M. W. A. Gonser, O. Elbjeirami, T. Grimes, T. R. Cundari, Inorg. Chem. 2005, 44, 8200-8210;
H. V. Rasika Dias, C. S. P. Gamage, Angew. Chem. Int. Ed. 2007, 46, 2192-2194;
Angew. Chem. 2007, 119, 2242-2244;
M. A. Rawashdeh-Omary, M. D. Rashdan, S. Dharanipathi, O. Elbjeirami, P. Ramesh, H. V. R. Dias, Chem. Commun. 2011, 47, 1160-1162;
N. B. Jayaratna, C. V. Hettiarachchi, M. Yousufuddin, H. V. R. Dias, New J. Chem. 2015, 39, 5092-5095;
N. B. Jayaratna, M. M. Olmstead, B. I. Kharisov, H. V. R. Dias, Inorg. Chem. 2016, 55, 8277-8280;
R. Hahn, F. Bohle, S. Kotte, T. J. Keller, S.-S. Jester, A. Hansen, S. Grimme, B. Esser, Chem. Sci. 2018, 9, 3477-3483;
R. Hahn, F. Bohle, W. Fang, A. Walther, S. Grimme, V. Esser, J. Am. Chem. Soc. 2018, 140, 17932-17944.
S. M. Tekarli, T. R. Cundari, M. A. Omary, J. Am. Chem. Soc. 2008, 130, 1669-1675.
T. R. Schulte, J. J. Holstein, L. Krause, R. Michel, D. Stalke, E. Sakuda, K. Umakoshi, G. Longhi, S. Abbate, G. H. Clever, J. Am. Chem. Soc. 2017, 139, 6863-6866.
K. Nishihara, M. Ueda, A. Higashitani, Y. Nakao, Y. Arikawa, S. Horiuchi, E. Sakuda, K. Umakoshi, Dalton Trans. 2016, 45, 4978-4982;
M. Ueda, S. Horiuchi, E. Sakuda, Y. Nakao, Y. Arikawa, K. Umakoshi, Chem. Commun. 2017, 53, 6405-6408;
S. Horiuchi, S. Moon, E. Sakuda, A. Ito, Y. Arikawa, K. Umakoshi, Dalton Trans. 2018, 47, 7113-7117;
S. Horiuchi, S. Tanaka, S. Moon, E. Sakuda, A. Ito, Y. Arikawa, K. Umakoshi, Inorg. Chem. 2021, 60, 1513-1522;
S. Horiuchi, K. Umakoshi, Chem. Rec. 2021, 21, 469-479.
M. Munakata, L. P. Wu, G. L. Ning, Coord. Chem. Rev. 2000, 198, 171-203;
H. V. R. Dias, M. Fianchini, T. R. Cundari, C. F. Campana, Angew. Chem. Int. Ed. 2008, 47, 556-559;
Angew. Chem. 2008, 120, 566-569;
M. Fianchini, H. Dai, H. V. R. Dias, Chem. Commun. 2009, 45, 6373-6375;
S. A. Baudron, Coord. Chem. Rev. 2019, 380, 318-329;
M. F. Ibad, A. Schulz, A. Villinger, Organometallics 2019, 38, 1445-1458.
The Mayer bond indices were calculated on a Multiwfn program, see: T. Lu, F. Chen, J. Comput. Chem. 2012, 33, 580-592.
O. Back, M. Henry-Ellinger, C. D. Martin, D. Martin, G. Bertrand, Angew. Chem. Int. Ed. 2013, 52, 2939-2943;
Angew. Chem. 2013, 125, 3011-3015;
D. J. Nelson, S. P. Nolan, Chem. Soc. Rev. 2013, 42, 6723-6753;
H. V. Huynh, Chem. Rev. 2018, 118, 9457-9492.
The crude reaction mixture after the demetalation reaction included both U- and Z-shaped isomers of 3 a. The solubility of 3 aU was significantly lower than that of 3 aZ, resulted in the selective crystallization of 3 aU from the mixture.
Pt2 and Pt2Ag2 complexes having cyclometallated NHC chelating ligands and Me2pz bridging ligands have been reported, see:
P. Pinter, Y. Unger, T. Strassner, ChemPhotoChem 2017, 1, 113-115;
L. Arnal, S. Fuertes, A. Martin, V. Sicilia, Chem. Eur. J. 2018, 24, 9377-9384.
T. Osuga, T. Murase, M. Fujita, Angew. Chem. Int. Ed. 2012, 51, 12199-12201;
Angew. Chem. 2012, 124, 12365-12367;
Y. Kohyama, T. Murase, M. Fujita, Angew. Chem. Int. Ed. 2014, 53, 11510-11513;
Angew. Chem. 2014, 126, 11694-11697;
A. Vellé, A. Cebollada, M. Iglesias, P. J. Sanz Miguel, Inorg. Chem. 2014, 53, 10654-10659;
B. Hua, L. Shao, Z. Zhang, J. Liu, F. Huang, J. Am. Chem. Soc. 2019, 141, 15008-15012.
Metal-metal interactions typically altered their emission properties of the complexes. For selected reviews, see:
V. W.-W. Yam, V. K.-M. Au, S. Y.-L. Leung, Chem. Rev. 2015, 115, 7589-7728;
H. B. Gray, S. Záliš, A. Vlček, Coord. Chem. Rev. 2017, 345, 297-317;
M. Yoshida, M. Kato, Coord. Chem. Rev. 2018, 355, 101-115.
The absorption spectra recorded in CH2Cl2 solutions derived from the mixture of isomers because of the rapid isomerization of the sandwich complexes.
For selected reviews of planer chirality, see:
Z. Hassan, E. Spuling, D. M. Knoll, J. Lahann, S. Bräse, Chem. Soc. Rev. 2018, 47, 6947-6963;
K. Yoshida, R. Yasue, Chem. Eur. J. 2018, 24, 18575-18586.
The multinuclear Ag complexes readily decomposed during HPLC techniques, probably because the Ag−N bonds are unstable under the conditions.
J. A. Raskatov, A. L. Thompson, A. R. Cowley, T. D. W. Claridge, J. M. Brown, Chem. Sci. 2013, 4, 3140-3147.
M. Deng, N. F. M. Mukthar, N. D. Schley, G. Ung, Angew. Chem. Int. Ed. 2020, 59, 1228-1231;
Angew. Chem. 2020, 132, 1244-1247;
J.-G. Yang, K. Li, J. Wang, S. Sun, W. Chi, C. Wang, X. Chang, C. Zou, W.-P. To, M.-D. Li, X. Liu, W. Lu, H.-X. Zhang, C.-M. Che, Y. Chen, Angew. Chem. Int. Ed. 2020, 59, 6915-6922;
Angew. Chem. 2020, 132, 6982-6989;
E. S. Gauthier, L. Abella, N. Hellou, B. Darquié, E. Caytan, T. Roisnel, N. Vanthuyne, L. Favereau, M. Srebro-Hooper, J. A. G. Williams, J. Autschbach, J. Crassous, Angew. Chem. Int. Ed. 2020, 59, 8394-8400;
Angew. Chem. 2020, 132, 8472-8478;
T. Ono, K. Ishihama, A. Taema, T. Harada, K. Furusho, M. Hasegawa, Y. Nojima, M. Abe, Y. Hisaeda, Angew. Chem. Int. Ed. 2021, 60, 2614-2618.
J. Kumar, T. Kawai, T. Nakashima, Chem. Commun. 2017, 53, 1269-1272;
Z. Han, X.-Y. Dong, P. Luo, S. Li, Z.-Y. Wang, S. Q. Zang, T. C. W. Mak, Sci. Adv. 2020, 6, eaay0107.