Synthesis of trifluoromethyl ketones by nucleophilic trifluoromethylation of esters under a fluoroform/KHMDS/triglyme system.
HFC-23
fluoroform
greenhouse gas
trifluoromethyl ketones
trifluoromethylation
Journal
Beilstein journal of organic chemistry
ISSN: 1860-5397
Titre abrégé: Beilstein J Org Chem
Pays: Germany
ID NLM: 101250746
Informations de publication
Date de publication:
2021
2021
Historique:
received:
03
11
2020
accepted:
02
02
2021
entrez:
26
2
2021
pubmed:
27
2
2021
medline:
27
2
2021
Statut:
epublish
Résumé
A straightforward method that enables the formation of biologically attractive trifluoromethyl ketones from readily available methyl esters using the potent greenhouse gas fluoroform (HCF
Identifiants
pubmed: 33633811
doi: 10.3762/bjoc.17.39
pmc: PMC7884878
doi:
Types de publication
Journal Article
Langues
eng
Pagination
431-438Informations de copyright
Copyright © 2021, Fujihira et al.
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