Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles.

X-ray spectroscopy density functional calculations iron metal clusters metal hydrides

Journal

ChemistryOpen
ISSN: 2191-1363
Titre abrégé: ChemistryOpen
Pays: Germany
ID NLM: 101594811

Informations de publication

Date de publication:
Feb 2021
Historique:
received: 10 10 2020
revised: 17 02 2021
entrez: 1 3 2021
pubmed: 2 3 2021
medline: 2 3 2021
Statut: ppublish

Résumé

The controlled assembly of well-defined planar nanoclusters from molecular precursors is synthetically challenging and often plagued by the predominant formation of 3D-structures and nanoparticles. Herein, we report planar iron hydride nanoclusters from reactions of main group element hydrides with iron(II) bis(hexamethyldisilazide). The structures and properties of isolated Fe

Identifiants

pubmed: 33646644
doi: 10.1002/open.202000307
pmc: PMC7919527
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

265-271

Subventions

Organisme : Deutsche Forschungsgemeinschaft
ID : 1708
Organisme : European Research Council
ID : 683150
Pays : International

Informations de copyright

© 2021 The Authors. Published by Wiley-VCH GmbH.

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Auteurs

Uttam Chakraborty (U)

Dept. of Chemistry, University of Hamburg Martin Luther King Pl. 6, 20146, Hamburg, Germany.

Patrick Bügel (P)

Institut für Nanotechnologie, Karlsruher Institut für Technologie (KIT), v.-Helmholtz Pl. 1, 76344, Eggenstein-Leopoldshafen, Germany.

Lorena Fritsch (L)

Dept. of Chemistry, Center for Sustainable Systems Design (CSSD), University of Paderborn, Warburger Str. 100, 33098, Paderborn, Germany.

Florian Weigend (F)

Institut für Nanotechnologie, Karlsruher Institut für Technologie (KIT), v.-Helmholtz Pl. 1, 76344, Eggenstein-Leopoldshafen, Germany.
Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Str. 4, 35032, Marburg, Germany.

Matthias Bauer (M)

Dept. of Chemistry, Center for Sustainable Systems Design (CSSD), University of Paderborn, Warburger Str. 100, 33098, Paderborn, Germany.

Axel Jacobi von Wangelin (A)

Dept. of Chemistry, University of Hamburg Martin Luther King Pl. 6, 20146, Hamburg, Germany.

Classifications MeSH