Hidden Mechanism Behind the Roughness-Enhanced Selectivity of Carbon Monoxide Electrocatalytic Reduction.
carbon monoxide reduction
electrocatalysis
kinetics
mechanistic studies
roughness
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
10 May 2021
10 May 2021
Historique:
received:
09
12
2020
pubmed:
5
3
2021
medline:
5
3
2021
entrez:
4
3
2021
Statut:
ppublish
Résumé
High roughness has been proved to be an effective design strategy for electrocatalyst in many systems. Especially, high selectivity of carbon monoxide reduction (CORR) in competition with the hydrogen evolution reaction has been observed on high roughness electrocatalysts. However, the two well-known mechanisms, i.e., decreasing the energy barrier of CORR and increasing local pH, failed to understand the roughness-enhanced selectivity in a recent experiment. Herein we unravel the hidden mechanism by establishing a comprehensive kinetic model for CORR on catalysts with different roughness factors. We conclude that the roughness-enhanced CORR selectivity is actually kinetic controlled by local-electric-field-directed mass transfer of adsorbed species on the electrode surface. Several ways to optimize CORR selectivity are predicted. Our work highlights the kinetics in electrocatalysis on nanocatalysts, and provides a conceptually new principle for future catalyst design.
Identifiants
pubmed: 33660382
doi: 10.1002/anie.202016332
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
11133-11137Subventions
Organisme : Ministry of Science and Technology of the People's Republic of China
ID : 2016YFA0400904
Organisme : Ministry of Science and Technology of the People's Republic of China
ID : 2018YFA0208702
Organisme : National Science Foundation of China
ID : 21973085
Organisme : National Science Foundation of China(CN)
ID : 21833007, 21790350, 21673212, 21521001
Organisme : Anhui Initiative in Quantum Information Technologies
ID : AHY090200
Organisme : National Science Foundation of China
ID : 21973085, 21833007, 21790350, 21673212, 21521001
Organisme : Fundamental Research Funds for the Central Universities
ID : WK2340000104
Informations de copyright
© 2021 Wiley-VCH GmbH.
Références
Z. W. Seh, J. Kibsgaard, C. F. Dickens, I. Chorkendorff, J. K. Norskov, T. F. Jaramillo, Science 2017, 355, eaad4998.
O. S. Bushuyev, P. De Luna, C. T. Dinh, L. Tao, G. Saur, J. van de Lagemaat, S. O. Kelley, E. H. Sargent, Joule 2018, 2, 825-832.
S. Xu, E. A. Carter, Chem. Rev. 2019, 119, 6631-6669.
D. D. Zhu, J. L. Liu, S. Z. Qiao, Adv. Mater. 2016, 28, 3423-3452.
T. Zheng, K. Jiang, H. Wang, Adv. Mater. 2018, 30, 1802066.
D. Gao, R. M. Arán-Ais, H. S. Jeon, B. Roldan Cuenya, Nat. Catal. 2019, 2, 198-210.
M. B. Ross, P. De Luna, Y. Li, C.-T. Dinh, D. Kim, P. Yang, E. H. Sargent, Nat. Catal. 2019, 2, 648-658.
Y. Hori, R. Takahashi, Y. Yoshinami, A. Murata, J. Phys. Chem. B 1997, 101, 7075-7081.
J. Feng, S. Zeng, J. Feng, H. Dong, X. Zhang, Chin. J. Chem. 2018, 36, 961-970.
A. Rendón-Calle, S. Builes, F. Calle-Vallejo, Curr. Opin. Electrochem. 2018, 9, 158-165.
W. Luc, X. Fu, J. Shi, J.-J. Lv, M. Jouny, B. H. Ko, Y. Xu, Q. Tu, X. Hu, J. Wu, Q. Yue, Y. Liu, F. Jiao, Y. Kang, Nat. Catal. 2019, 2, 423-430.
M. Jouny, W. Luc, F. Jiao, Nat. Catal. 2018, 1, 748-755.
Y. Pang, J. Li, Z. Wang, C.-S. Tan, P.-L. Hsieh, T.-T. Zhuang, Z.-Q. Liang, C. Zou, X. Wang, P. De Luna, J. P. Edwards, Y. Xu, F. Li, C.-T. Dinh, M. Zhong, Y. Lou, D. Wu, L.-J. Chen, E. H. Sargent, D. Sinton, Nat. Catal. 2019, 2, 251-258.
T.-T. Zhuang, Y. Pang, Z.-Q. Liang, Z. Wang, Y. Li, C.-S. Tan, J. Li, C. T. Dinh, P. De Luna, P.-L. Hsieh, T. Burdyny, H.-H. Li, M. Liu, Y. Wang, F. Li, A. Proppe, A. Johnston, D.-H. Nam, Z.-Y. Wu, Y.-R. Zheng, A. H. Ip, H. Tan, L.-J. Chen, S.-H. Yu, S. O. Kelley, D. Sinton, E. H. Sargent, Nat. Catal. 2018, 1, 946-951.
J. Li, F. Che, Y. Pang, C. Zou, J. Y. Howe, T. Burdyny, J. P. Edwards, Y. Wang, F. Li, Z. Wang, P. De Luna, C. T. Dinh, T. T. Zhuang, M. I. Saidaminov, S. Cheng, T. Wu, Y. Z. Finfrock, L. Ma, S. H. Hsieh, Y. S. Liu, G. A. Botton, W. F. Pong, X. Du, J. Guo, T. K. Sham, E. H. Sargent, D. Sinton, Nat. Commun. 2018, 9, 4614.
Y.-J. Zhang, V. Sethuraman, R. Michalsky, A. A. Peterson, ACS Catal. 2014, 4, 3742-3748.
A. A. Peterson, J. K. Nørskov, J. Phys. Chem. Lett. 2012, 3, 251-258.
C. W. Li, J. Ciston, M. W. Kanan, Nature 2014, 508, 504-507.
S. H. Lee, I. Sullivan, D. M. Larson, G. Liu, F. M. Toma, C. Xiang, W. S. Drisdell, ACS Catal. 2020, 10, 8000-8011.
M. Ma, B. J. Trzesniewski, J. Xie, W. A. Smith, Angew. Chem. Int. Ed. 2016, 55, 9748-9752;
Angew. Chem. 2016, 128, 9900-9904.
R. Kas, R. Kortlever, H. Yılmaz, M. T. M. Koper, G. Mul, ChemElectroChem 2015, 2, 354-358.
X. Wang, C. Xu, M. Jaroniec, Y. Zheng, S. Z. Qiao, Nat. Commun. 2019, 10, 4876.
B. A. Zhang, T. Ozel, J. S. Elias, C. Costentin, D. G. Nocera, ACS Cent. Sci. 2019, 5, 1097-1105.
L. Wang, S. Nitopi, A. B. Wong, J. L. Snider, A. C. Nielander, C. G. Morales-Guio, M. Orazov, D. C. Higgins, C. Hahn, T. F. Jaramillo, Nat. Catal. 2019, 2, 702-708.
A. Auer, M. Andersen, E.-M. Wernig, N. G. Hörmann, N. Buller, K. Reuter, J. Kunze-Liebhäuser, Nat. Catal. 2020, 3, 797-803.
C. Choi, S. Kwon, T. Cheng, M. Xu, P. Tieu, C. Lee, J. Cai, H. M. Lee, X. Pan, X. Duan, W. A. Goddard, Y. Huang, Nat. Catal. 2020, 3, 804-812 .
T. Kim, G. T. R. Palmore, Nat. Commun. 2020, 11, 3622.
H. Jiang, Z. Hou, Y. Luo, Angew. Chem. Int. Ed. 2017, 56, 15617-15621;
Angew. Chem. 2017, 129, 15823-15827.
M. Liu, Y. Pang, B. Zhang, P. De Luna, O. Voznyy, J. Xu, X. Zheng, C. T. Dinh, F. Fan, C. Cao, F. P. de Arquer, T. S. Safaei, A. Mepham, A. Klinkova, E. Kumacheva, T. Filleter, D. Sinton, S. O. Kelley, E. H. Sargent, Nature 2016, 537, 382-386.
Q.-X. Chen, Y.-H. Liu, X.-Z. Qi, J.-W. Liu, H.-J. Jiang, J.-L. Wang, Z. He, X.-F. Ren, Z.-H. Hou, S.-H. Yu, J. Am. Chem. Soc. 2019, 141, 10729-10735.
R. Subbaraman, D. Tripkovic, D. Strmcnik, K.-C. Chang, M. Uchimura, A. P. Paulikas, V. Stamenkovic, N. M. Markovic, Science 2011, 334, 1256-1260.
S. Sharifi-Asl, D. D. Macdonald, J. Electrochem. Soc. 2013, 160, H382-H391.
E. Liu, J. Li, L. Jiao, H. T. T. Doan, Z. Liu, Z. Zhao, Y. Huang, K. M. Abraham, S. Mukerjee, Q. Jia, J. Am. Chem. Soc. 2019, 141, 3232-3239.
J. Li, X. Li, C. M. Gunathunge, M. M. Waegele, Proc. Natl. Acad. Sci. USA 2019, 116, 9220-9229.
J. D. Roth, M. J. Weaver, Langmuir 1992, 8, 1451-1458.
H. Daiguji, Chem. Soc. Rev. 2010, 39, 901-911.