Complex coacervation of food grade antimicrobial lauric arginate with lambda carrageenan.

Catanionic micelles Foam Isothermal titration calorimetry Small angle X ray scattering Surfactant bilayers Teubner-strey structure factor model Turbidity Zetapotential

Journal

Current research in food science
ISSN: 2665-9271
Titre abrégé: Curr Res Food Sci
Pays: Netherlands
ID NLM: 101771059

Informations de publication

Date de publication:
2021
Historique:
received: 19 12 2020
revised: 23 01 2021
accepted: 29 01 2021
entrez: 5 3 2021
pubmed: 6 3 2021
medline: 6 3 2021
Statut: epublish

Résumé

In this study, the complex coacervation mechanism of Lauric arginate ester (LAE) with λ-carrageenan was studied using turbidimetry, light scattering and electrophoresis. The complexes formed were found to have a bilayer-like structure using small angle X-ray scattering (SAXS) and cryo-TEM (transmission electron microscopy). It was observed that mixing LAE with Sodium dodecyl sulfate (SDS) could significantly reduce the interactions between mixed micelles and λ-carrageenan. The interactions between LAE/SDS and λ-carrageenan were found to be predominantly entropy driven. Mixed micelles of LAE/Tween 20 and LAE/SDS showed significantly less interactions with carrageenan compared to pure LAE micelles. Interfacial properties of complexes were measured using surface tension measurements. It was observed that pure LAE showed good foaming behavior and when mixed with increasing amounts of carrageenan the foaming capacity decreased. Reduction in foam volume was due to reduced availability of free LAE molecules for foam stabilization and due to hydrophilic nature of complexes.

Identifiants

pubmed: 33665619
doi: 10.1016/j.crfs.2021.01.003
pii: S2665-9271(21)00004-6
pmc: PMC7902899
doi:

Types de publication

Journal Article

Langues

eng

Pagination

53-62

Informations de copyright

© 2021 The Author(s).

Déclaration de conflit d'intérêts

The authors declare that they have no known competing financialinterestsor personal relationships that could have appeared to influence the work reported in this paper.

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Auteurs

Trivikram Nallamilli (T)

Max Planck Institute for Polymer Research, Ackermannweg 10, 55128, Mainz, Germany.

Markus Ketomaeki (M)

Max Planck Institute for Polymer Research, Ackermannweg 10, 55128, Mainz, Germany.

Domenik Prozeller (D)

Max Planck Institute for Polymer Research, Ackermannweg 10, 55128, Mainz, Germany.

Julian Mars (J)

Max Planck Institute for Polymer Research, Ackermannweg 10, 55128, Mainz, Germany.

Svenja Morsbach (S)

Max Planck Institute for Polymer Research, Ackermannweg 10, 55128, Mainz, Germany.

Markus Mezger (M)

Max Planck Institute for Polymer Research, Ackermannweg 10, 55128, Mainz, Germany.

Thomas Vilgis (T)

Max Planck Institute for Polymer Research, Ackermannweg 10, 55128, Mainz, Germany.

Classifications MeSH