Modelling of impact of presence/absence of suspended particulate organic matter from river and sea and effluent wastewater on fluorescence signal in the coastal area of Gapeau River.
Fluorescence spectroscopy
Mixing experiments
Parallel factor analysis (PARAFAC) modelling
Solar irradiation
Suspended particulate organic matter (SPOM)
Journal
Environmental science and pollution research international
ISSN: 1614-7499
Titre abrégé: Environ Sci Pollut Res Int
Pays: Germany
ID NLM: 9441769
Informations de publication
Date de publication:
Jul 2021
Jul 2021
Historique:
received:
07
12
2020
accepted:
01
03
2021
pubmed:
13
3
2021
medline:
16
7
2021
entrez:
12
3
2021
Statut:
ppublish
Résumé
Organic matter has an important role in biogeochemistry in aquatic environments. This study investigated impact of suspended particulate organic matter (SPOM) on fluorescence signal of mixtures of three water types (river water RW, sea water SW, effluent wastewater WW) using fluorescence (excitation-emission matrix, EEM) spectroscopy and parallel factor analysis (PARAFAC) and multilinear regression. Four irradiation experiments (Expt-1, Expt-2, Expt-3, and Expt-4) were conducted during different times of the year ( two in autumn, one in winter, and one in spring season). Samples were exposed to natural sunlight on laboratory rooftop in University of Toulon, France, with another set of samples kept in dark as control samples. Three component (C1, C2, C3) model was validated by split-half and Concordia from the whole EEM dataset of all irradiation experiments. No protein-like fluorophores was found. The study revealed the effect of SPOM presence/absence on fluorescence signal of DOM and on resulting parameters of multilinear regression MLR model and kinetic constant of these MLR parameters. Kinetic constant (k) for all MLR coefficients was in order of greatness as Expt-1 (SPOM of WW only in mixtures) > Expt-3 (SPOM of SW only in mixtures) > Expt-2 (SPOM of RW only in mixtures)> Expt-4 (SPOM of RW + SW + WW in mixtures) indicating that SPOM of WW is the most resistant to photodegradation. For dark control samples, only relative standard deviation RSD could be calculated from dataset. RSD values for C3 were the highest indicating its chaotic variations, and the lowest RSD values were found for both C1 and C2 for all experiments. Statistical differences has been found between control and irradiated experiments. These models developed in this study can be used to predict fluorescence signal of anthropogenic effluent DOM during its transport in river systems to coastal zone.
Identifiants
pubmed: 33709309
doi: 10.1007/s11356-021-13265-2
pii: 10.1007/s11356-021-13265-2
doi:
Substances chimiques
Humic Substances
0
Particulate Matter
0
Waste Water
0
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
36707-36726Subventions
Organisme : Erasmus Mundus
ID : HERMES PROGRAMME/ PHD SCHOLARSHIP
Organisme : Campus France (FR)
ID : Al Maqdisi PHC Project n° 40229SD
Informations de copyright
© 2021. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.
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