Synthesis of Yttrium Superhydride Superconductor with a Transition Temperature up to 262 K by Catalytic Hydrogenation at High Pressures.


Journal

Physical review letters
ISSN: 1079-7114
Titre abrégé: Phys Rev Lett
Pays: United States
ID NLM: 0401141

Informations de publication

Date de publication:
19 Mar 2021
Historique:
received: 17 11 2020
accepted: 19 01 2021
entrez: 2 4 2021
pubmed: 3 4 2021
medline: 3 4 2021
Statut: ppublish

Résumé

The recent observation of room-temperature superconductivity will undoubtedly lead to a surge in the discovery of new, dense, hydrogen-rich materials. The rare earth metal superhydrides are predicted to have very high-T_{c} superconductivity that is tunable with changes in stoichiometry or doping. Here we report the synthesis of an yttrium superhydride that exhibits superconductivity at a critical temperature of 262 K at 182±8  GPa. A palladium thin film assists the synthesis by protecting the sputtered yttrium from oxidation and promoting subsequent hydrogenation. Phonon-mediated superconductivity is established by the observation of zero resistance, an isotope effect and the reduction of T_{c} under an external magnetic field. The upper critical magnetic field is 103 T at zero temperature.

Identifiants

pubmed: 33798352
doi: 10.1103/PhysRevLett.126.117003
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

117003

Subventions

Organisme : NIH HHS
ID : S10 OD024973
Pays : United States
Organisme : NCRR NIH HHS
ID : S10 RR028863
Pays : United States

Auteurs

Elliot Snider (E)

Department of Mechanical Engineering, School of Engineering and Applied Sciences, University of Rochester, Rochester, New York 14627, USA.

Nathan Dasenbrock-Gammon (N)

Department of Physics and Astronomy, University of Rochester, Rochester, New York 14627, USA.

Raymond McBride (R)

Department of Mechanical Engineering, School of Engineering and Applied Sciences, University of Rochester, Rochester, New York 14627, USA.

Xiaoyu Wang (X)

Department of Chemistry, State University of New York at Buffalo, Buffalo, New York 14260, USA.

Noah Meyers (N)

Department of Mechanical Engineering, School of Engineering and Applied Sciences, University of Rochester, Rochester, New York 14627, USA.

Keith V Lawler (KV)

Department of Chemistry & Biochemistry, University of Nevada Las Vegas, Las Vegas, Nevada 89154, USA.

Eva Zurek (E)

Department of Chemistry, State University of New York at Buffalo, Buffalo, New York 14260, USA.

Ashkan Salamat (A)

Department of Physics & Astronomy, University of Nevada Las Vegas, Las Vegas, Nevada 89154, USA.

Ranga P Dias (RP)

Department of Mechanical Engineering, School of Engineering and Applied Sciences, University of Rochester, Rochester, New York 14627, USA.
Department of Physics and Astronomy, University of Rochester, Rochester, New York 14627, USA.

Classifications MeSH