Large scale synthesis of copper nickel alloy nanoparticles with reduced compressibility using arc thermal plasma process.


Journal

Scientific reports
ISSN: 2045-2322
Titre abrégé: Sci Rep
Pays: England
ID NLM: 101563288

Informations de publication

Date de publication:
07 Apr 2021
Historique:
received: 24 10 2020
accepted: 17 03 2021
entrez: 8 4 2021
pubmed: 9 4 2021
medline: 9 4 2021
Statut: epublish

Résumé

Among the various methods employed in the synthesis of nanostructures, those involving high operating temperature and sharp thermal gradients often lead to the establishment of new exotic properties. Herein, we report on the formation of Cu-Ni metallic alloy nanoparticles with greatly enhanced stiffness achieved through direct-current transferred arc-thermal plasma assisted vapour-phase condensation. High pressure synchrotron X-ray powder diffraction (XRPD) at ambient temperature as well as XRPD in the temperature range 180 to 920 K, show that the thermal arc-plasma route resulted in alloy nanoparticles with much enhanced bulk modulus compared to their bulk counterparts. Such a behaviour may find an explanation in the sudden quenching assisted by the retention of a large amount of local strain due to alloying, combined with the perfect miscibility of the elemental components during the thermal plasma synthesis process.

Identifiants

pubmed: 33828126
doi: 10.1038/s41598-021-86776-0
pii: 10.1038/s41598-021-86776-0
pmc: PMC8026964
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

7629

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Auteurs

Subrat Kumar Das (SK)

Atmospheric Plasma Division, Institute for Plasma Research, Gandhinagar, 382016, India.

Arkaprava Das (A)

Atmospheric Plasma Division, Institute for Plasma Research, Gandhinagar, 382016, India.

Mattia Gaboardi (M)

Elettra-Sincrotrone Trieste, S.S. 14, Km 163.5 in Area Science Park, 34149, Basovizza, Italy.

Simone Pollastri (S)

Elettra-Sincrotrone Trieste, S.S. 14, Km 163.5 in Area Science Park, 34149, Basovizza, Italy.

G D Dhamale (GD)

Atmospheric Plasma Division, Institute for Plasma Research, Gandhinagar, 382016, India.

C Balasubramanian (C)

Atmospheric Plasma Division, Institute for Plasma Research, Gandhinagar, 382016, India. balac@ipr.res.in.
Homi Bhabha National Institute, Anushakti Nagar, Mumbai, 400 094, India. balac@ipr.res.in.

Boby Joseph (B)

Elettra-Sincrotrone Trieste, S.S. 14, Km 163.5 in Area Science Park, 34149, Basovizza, Italy. boby.joseph@elettra.eu.

Classifications MeSH