Toward a deeper and simpler understanding of serum protein-mediated transformations of magnetic nanoparticles by ICP-MS.

Human serum ICP-MS Magnetic nanoparticles Magnetic separation Metal-containing proteins Protein corona

Journal

Talanta
ISSN: 1873-3573
Titre abrégé: Talanta
Pays: Netherlands
ID NLM: 2984816R

Informations de publication

Date de publication:
01 Jul 2021
Historique:
received: 25 01 2021
revised: 03 03 2021
accepted: 06 03 2021
entrez: 11 4 2021
pubmed: 12 4 2021
medline: 1 5 2021
Statut: ppublish

Résumé

A great variety of magnetic nanomaterials are entering preclinical investigations with the objective to select the most promising candidates for diagnostic and therapeutic applications. For an analytical approach to be used as a high-throughput screening tool, simple and cost-efficient sample preparation protocol is a basiс prerequisite. Here, we demonstrate how the application of continuous magnetic field allows for quantitatively separating iron oxide magnetic nanoparticles from a mixture with human serum to facilitate monitoring of their biomolecular interactions with high-resolution inductively coupled plasma mass spectrometry. By measuring the signals of sulfur and metal isotopes, it is possible to monitor the formation of the protein corona and alterations in the concentrations of relevant metals due to binding of specific metalloproteins, respectively.

Identifiants

pubmed: 33838780
pii: S0039-9140(21)00208-3
doi: 10.1016/j.talanta.2021.122287
pii:
doi:

Substances chimiques

Blood Proteins 0
Magnetite Nanoparticles 0
Metalloproteins 0
Metals 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

122287

Informations de copyright

Copyright © 2021 Elsevier B.V. All rights reserved.

Auteurs

Olga V Kuznetsova (OV)

Vernadsky Institute of Geochemistry and Analytical Chemistry, 119991, Moscow, Russian Federation.

Maciej Jarosz (M)

Chair of Analytical Chemistry, Warsaw University of Technology, 00664, Warsaw, Poland.

Bernhard K Keppler (BK)

Institute of Inorganic Chemistry, University of Vienna, 1090, Vienna, Austria.

Andrei R Timerbaev (AR)

Vernadsky Institute of Geochemistry and Analytical Chemistry, 119991, Moscow, Russian Federation. Electronic address: andrei.timerbaev@univie.ac.at.

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Classifications MeSH