Large-Area Crystalline Zeolitic Imidazolate Framework Thin Films.

ZIF-67 crystallization metal-organic frameworks thin films

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
14 Jun 2021
Historique:
received: 29 03 2021
pubmed: 16 4 2021
medline: 16 4 2021
entrez: 15 4 2021
Statut: ppublish

Résumé

We report that continuous MOF films with highly controlled thickness (from 44 to 5100 nm) can be deposited over length scales greater than 80 centimeters by a facile, fast, and cost-effective spray-coating method. Such success relies on our discovery of unprecedented perfectly dispersed colloidal solutions consisting of amorphous MOF nanoparticles, which we adopted as precursors that readily converted to the crystalline films upon low-temperature in situ heating. The colloidal solutions allow for the fabrication of compact and uniform MOF films on a great deal of substrates such as fluorine-doped tin oxide, glass, SiO

Identifiants

pubmed: 33856098
doi: 10.1002/anie.202104366
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

14124-14130

Informations de copyright

© 2021 Wiley-VCH GmbH.

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Auteurs

Zhi Chen (Z)

Division of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Institute of Energy, Hefei Comprehensive National Science Center, CAS Center for Excellence in Nanoscience, Institute of Biomimetic Materials & Chemistry, Anhui Engineering Laboratory of Biomimetic Materials, Department of Chemistry, University of Science and Technology of China, Hefei, 230026, China.

Rui Wang (R)

Division of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Institute of Energy, Hefei Comprehensive National Science Center, CAS Center for Excellence in Nanoscience, Institute of Biomimetic Materials & Chemistry, Anhui Engineering Laboratory of Biomimetic Materials, Department of Chemistry, University of Science and Technology of China, Hefei, 230026, China.

Tao Ma (T)

Shenzhen Key Laboratory for Functional Polymer, College of Chemistry and Environment Engineering, Shenzhen University, Shenzhen, Guangdong, 518060, China.

Jin-Long Wang (JL)

Division of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Institute of Energy, Hefei Comprehensive National Science Center, CAS Center for Excellence in Nanoscience, Institute of Biomimetic Materials & Chemistry, Anhui Engineering Laboratory of Biomimetic Materials, Department of Chemistry, University of Science and Technology of China, Hefei, 230026, China.

Yu Duan (Y)

Division of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Institute of Energy, Hefei Comprehensive National Science Center, CAS Center for Excellence in Nanoscience, Institute of Biomimetic Materials & Chemistry, Anhui Engineering Laboratory of Biomimetic Materials, Department of Chemistry, University of Science and Technology of China, Hefei, 230026, China.

Zhi-Zhan Dai (ZZ)

Hefei National Laboratory for Physical Sciences at the Microscale, Department of Physics, and CAS Key Laboratory of Strongly-coupled Quantum Matter Physics, University of Science and Technology of China, Hefei, 230026, China.

Jie Xu (J)

Institute of Functional Nano and Soft Materials (FUNSOM) & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, 215123, China.

Hui-Juan Wang (HJ)

Experimental Center of Engineering and Material Science, University of Science and Technology of China, Hefei, 230026, China.

Jiayin Yuan (J)

Department of Materials and Environmental Chemistry, Stockholm University, 10691, Stockholm, Sweden.

Hai-Long Jiang (HL)

Division of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Institute of Energy, Hefei Comprehensive National Science Center, CAS Center for Excellence in Nanoscience, Institute of Biomimetic Materials & Chemistry, Anhui Engineering Laboratory of Biomimetic Materials, Department of Chemistry, University of Science and Technology of China, Hefei, 230026, China.

Yue-Wei Yin (YW)

Hefei National Laboratory for Physical Sciences at the Microscale, Department of Physics, and CAS Key Laboratory of Strongly-coupled Quantum Matter Physics, University of Science and Technology of China, Hefei, 230026, China.

Xiao-Guang Li (XG)

Hefei National Laboratory for Physical Sciences at the Microscale, Department of Physics, and CAS Key Laboratory of Strongly-coupled Quantum Matter Physics, University of Science and Technology of China, Hefei, 230026, China.
Collaborative Innovation Center of Advanced Microstructures, Nanjing, 210093, China.

Min-Rui Gao (MR)

Division of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Institute of Energy, Hefei Comprehensive National Science Center, CAS Center for Excellence in Nanoscience, Institute of Biomimetic Materials & Chemistry, Anhui Engineering Laboratory of Biomimetic Materials, Department of Chemistry, University of Science and Technology of China, Hefei, 230026, China.

Shu-Hong Yu (SH)

Division of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Institute of Energy, Hefei Comprehensive National Science Center, CAS Center for Excellence in Nanoscience, Institute of Biomimetic Materials & Chemistry, Anhui Engineering Laboratory of Biomimetic Materials, Department of Chemistry, University of Science and Technology of China, Hefei, 230026, China.

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