Modular Toolkit of Multifunctional Block Copoly(2-oxazoline)s for the Synthesis of Nanoparticles.
block copolymers
click chemistry
nanoparticles
ring-opening polymerization
surfactants
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
04 Jun 2021
04 Jun 2021
Historique:
received:
14
04
2021
pubmed:
21
4
2021
medline:
21
4
2021
entrez:
20
4
2021
Statut:
ppublish
Résumé
Post-polymerization modification provides an elegant way to introduce chemical functionalities onto macromolecules to produce tailor-made materials with superior properties. This concept was adapted to well-defined block copolymers of the poly(2-oxazoline) family and demonstrated the large potential of these macromolecules as universal toolkit for numerous applications. Triblock copolymers with separated water-soluble, alkyne- and alkene-containing segments were synthesized and orthogonally modified with various low-molecular weight functional molecules by copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) and thiol-ene (TE) click reactions, respectively. Representative toolkit polymers were used for the synthesis of gold, iron oxide and silica nanoparticles.
Identifiants
pubmed: 33878222
doi: 10.1002/chem.202101327
pmc: PMC8252465
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
8283-8287Informations de copyright
© 2021 The Authors. Published by Wiley-VCH GmbH.
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